Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom

doi:10.1039/d0ee03575k

	Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom
	Sun, Ruiyan 1; Liao, Yuhe 1,3; Bai, Shao-Tao 1; Zheng, Mingyuan 2; Zhou, Cheng 1; Zhang, Tao 2; Sels, Bert F.1
刊名	ENERGY & ENVIRONMENTAL SCIENCE
	2021-03-01
卷号	14 期号:3 页码:1247-1285
ISSN号	1754-5692
DOI	10.1039/d0ee03575k
通讯作者	Zhang, Tao(taozhang@dicp.ac.cn) ; Sels, Bert F.(bert.sels@kuleuven.be)
英文摘要	Propelled by the vision of carbon-neutral energy systems, heterogeneous hydrogenation of CO2 to formic acid/formate, a liquid hydrogen carrier, has been intensively studied as a promising approach to realize renewable and decarbonized energy supply. In the present review, the state-of-the-art of heterogeneous catalysts for this process is comprehensively summarized. First, a brief description of the challenges associated with thermodynamics is provided. Major advancements on constructing efficient heterogeneous catalysts then constitute the main body of this review, mainly involving nanostructured and single atom catalysts based on noble metals. Special attention is paid to the relevant structure-activity correlations and mechanistic insights, which provide strong bases for rational catalyst design. Key factors related to catalytic activity are highlighted including metal dispersion, electron density, basic functionalities, and concerted catalysis of metal and basic sites. A summary and outlook is presented in the end. We believe that this review will inspire more novel research from the catalysis community to advance the design of innovative catalytic materials towards the ultimate sustainable energy sector with a closed carbon loop.
资助项目	KU Leuven through the C2 research program ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801] ; National Natural Science Foundation of China[21690081] ; Biorefineries Featuring Carbon Dioxide Capturing and Utilization Project
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000639555200006
资助机构	KU Leuven through the C2 research program ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; Biorefineries Featuring Carbon Dioxide Capturing and Utilization Project
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/32974]
专题	中国科学院广州能源研究所
通讯作者	Zhang, Tao; Sels, Bert F.
作者单位	1.Katholieke Univ Leuven, Fac Biosci, Ctr Sustainable Catalysis & Engn, Celestijnenlaan 200F, B-3001 Heverlee, Belgium 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Sun, Ruiyan,Liao, Yuhe,Bai, Shao-Tao,et al. Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom[J]. ENERGY & ENVIRONMENTAL SCIENCE,2021,14(3):1247-1285.
APA	Sun, Ruiyan.,Liao, Yuhe.,Bai, Shao-Tao.,Zheng, Mingyuan.,Zhou, Cheng.,...&Sels, Bert F..(2021).Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom.ENERGY & ENVIRONMENTAL SCIENCE,14(3),1247-1285.
MLA	Sun, Ruiyan,et al."Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom".ENERGY & ENVIRONMENTAL SCIENCE 14.3(2021):1247-1285.