Constructing electron pathways by graphene oxide for V2O5 nanoparticles in ultrahigh-performance and fast charging aqueous zinc ion batteries | |
Wu, Shougang1,2; Liu, Shuang1,2; Hu, Linhua2; Chen, Shuanghong2 | |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS |
2021-10-15 | |
卷号 | 878 |
关键词 | Aqueous zinc ion batteries V2O5/GO composite High-performance Fast charging |
ISSN号 | 0925-8388 |
DOI | 10.1016/j.jallcom.2021.160324 |
通讯作者 | Chen, Shuanghong(shchen@rntek.cas.cn) |
英文摘要 | Vanadium pentoxide (V2O5) materials show great promise in rechargeable aqueous zinc ion batteries (ZIBs) from its outstanding theoretical capacity. Limited to the poor electronic conductivity and sluggish ionic diffusion kinetics, most of the V2O5-based cathodes exhibit unsatisfactory specific capacity and short life span. Herein, V2O5/graphene oxide composite (V2O5/GO),which V2O5 nanoparticles in-situ grow on GO plates, are facile synthesized as cathodes for ZIBs. The V2O5/GO heterojunctions have a continuous electron transfer pathways and abundant Zn2+ insertion active sites, a capacitive-controlled kinetics, and an improved hydrophilicity. As a result, this V2O5/GO-ZIBs display an admirable capacity of 525 mAh g(-1) at 0.1 A g(-1), remarkable rate capability of 114 mAh g(-1) at 40 A g(-1), long lifespan up to 10,000 cycles at 20 A g(-1) with 90.8% retention, extreme-fast charging ability of 12.8 s at 40 A g(-1), greatly outperform most of reported ZIBs. Therefore, this work may guide the commercial application of ZIBs based on the superior performance and the simple synthesis approach. (C) 2021 Elsevier B.V. All rights reserved. |
资助项目 | Anhui Provincial Natural Science Foundation[2008085ME135] ; CASHIPS Director's Fund[YZJJ201902] ; CASHIPS Director's Fund[YZJJZX202018] |
WOS关键词 | HIGH-CAPACITY ; CATHODE ; ENERGY |
WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000660466600001 |
资助机构 | Anhui Provincial Natural Science Foundation ; CASHIPS Director's Fund |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/123950] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Chen, Shuanghong |
作者单位 | 1.Univ Sci & Technol China, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Key Lab Photovolta & Energy Conservat Mat, HFIPS, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Shougang,Liu, Shuang,Hu, Linhua,et al. Constructing electron pathways by graphene oxide for V2O5 nanoparticles in ultrahigh-performance and fast charging aqueous zinc ion batteries[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2021,878. |
APA | Wu, Shougang,Liu, Shuang,Hu, Linhua,&Chen, Shuanghong.(2021).Constructing electron pathways by graphene oxide for V2O5 nanoparticles in ultrahigh-performance and fast charging aqueous zinc ion batteries.JOURNAL OF ALLOYS AND COMPOUNDS,878. |
MLA | Wu, Shougang,et al."Constructing electron pathways by graphene oxide for V2O5 nanoparticles in ultrahigh-performance and fast charging aqueous zinc ion batteries".JOURNAL OF ALLOYS AND COMPOUNDS 878(2021). |
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