Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions

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	Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions
	Zheng LQ(郑利强); Zhu WZ; Shen Q; Shui LL; Li GZ; Sun ZW(孙祉伟)
刊名	Colloids and Surfaces A: Physicochemical and Engineering Aspects
	2002
卷号	201 期号:13 页码:111-121
ISSN号	0927-7757
英文摘要	The kinetic studies of the acrylic octadecyl ester and styrene polymerization in microemulsion systems, (1) cetyl pyridine bromide (CPDB)/t-butanol/styrene/water; (2) CPDB/t-butanol/toluene + acrylic octadecyl ester (1:1, w/v)/ water; (3) cetyl pyridine bromide/styrene/formamide, were made by using dynamic laser light scattering techniques (DLS). The mechanisms of nucleation of latex particles were discussed. The most possible nucleation location of the styrene and acrylic octadecyl ester microlatex particles in aqueous microemulsion system is in aqueous phase via homogeneous nucleation. Meanwhile, parts of microlatex particles are possibly produced via swollen micelles (microemulsions) and monomer droplets nucleation. On the other hand, the most possible nucleation location of the styrene microlatex particles in nonaqueous microemulsion system is inside monomer droplets. The relationship between the amount of monomer and the size of microlatex was also investigated. It has been found that the size of microlatex particles could be controlled by changing the amount of monomer. (C) 2002 Elsevier Science B.V. All rights reserved.
学科主题	力学
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry ; Polymer Science
收录类别	SCI
语种	英语
WOS记录号	WOS:000174783800011
公开日期	2007-06-15 ; 2007-12-05 ; 2009-06-23
内容类型	期刊论文
源URL	[http://dspace.imech.ac.cn/handle/311007/16035]
专题	力学研究所_力学所知识产出(1956-2008)
推荐引用方式 GB/T 7714	Zheng LQ,Zhu WZ,Shen Q,et al. Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2002,201(13):111-121.
APA	郑利强,Zhu WZ,Shen Q,Shui LL,Li GZ,&孙祉伟.(2002).Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions.Colloids and Surfaces A: Physicochemical and Engineering Aspects,201(13),111-121.
MLA	郑利强,et al."Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions".Colloids and Surfaces A: Physicochemical and Engineering Aspects 201.13(2002):111-121.