The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge | |
Yang, Y (Yang, Yun)[ 1 ]; Dong, XY (Dong, Xiaoyu)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]; Wu, HP (Wu, Hongping)[ 1 ] | |
刊名 | INORGANIC CHEMISTRY
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2018 | |
卷号 | 57期号:21页码:13380-13385 |
ISSN号 | 0020-1669 |
DOI | 10.1021/acs.inorgchem.8b01960 |
英文摘要 | The first rubidium barium borate, RbBaB7O12, has been prepared. Through analysis of single crystal structures, RbBaB7O12 is built from a three-dimensional [B7O12](infinity) framework with two types of channels which are occupied by Rb+ and Ba2+ ions. The connection style of the fundamental building block (FBB) B7O15 is different from that of B-O FBBs existing in the other borates, which can be determined as the unprecedented unit. The structural performance relationship can be better understood by combining first-principles calculations and experimental results. For the RbBaB7O12, the indirect energy gap is 5.96 eV, which matches the experimental data (wavelength absorption < 190 nm). IR spectroscopy and thermal analysis have also been characterized. What's more, for all the available anhydrous hepta-borates, the structure comparisons about FBBs were carried out. |
WOS记录号 | WOS:000449576900037 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7716] ![]() |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Pan, SL (Pan, Shilie)[ 1 ] |
作者单位 | Xinjiang Tech Inst Phys & Chem, CAS Xinjiang Key Lab Elect Informat Mat & Devices, CAS Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Y ,Dong, XY ,Pan, SL ,et al. The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge[J]. INORGANIC CHEMISTRY,2018,57(21):13380-13385. |
APA | Yang, Y ,Dong, XY ,Pan, SL ,&Wu, HP .(2018).The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge.INORGANIC CHEMISTRY,57(21),13380-13385. |
MLA | Yang, Y ,et al."The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge".INORGANIC CHEMISTRY 57.21(2018):13380-13385. |
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