Ba-3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High-Temperature Solution Method | |
Huang, CM (Huang, Chunmei)[ 1,2 ]; Zhang, FF (Zhang, Fangfang)[ 1,2 ]; Cheng, SC (Cheng, Shichao)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ]; Li, H (Li, Hao)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1,2 ] | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL |
2020 | |
卷号 | 26期号:70页码:16628-16632 |
关键词 | borate carbonate borate fluoride first-principle calculations synthesis |
ISSN号 | 0947-6539 |
DOI | 10.1002/chem.202003606 |
英文摘要 | In contrast to the well-investigated halogen-containing borates and carbonates, very few halogen-containing borate carbonate compounds have been reported. Specifically, no example of borate carbonate fluoride has been synthesized successfully until now. Herein, the planar pi-conjugated units [BO3](3-) and [CO3](2-) and the F- ions are introduced simultaneously into one crystal structure resulting in the first borate carbonate fluoride, Ba-3(BO3)(CO3)F, by the high-temperature solution method in the atmosphere. Its structure features a hexagonal channel formed by the [BO3](3-) and [CO3](2-) units with the [F3Ba8](13+) trimers filled in the channel. Various characterizations including single crystal- and powder-XRD, EDX, IR, UV-vis-NIR, and TG-DSC, together with the first principles calculation have been carried out to verify the structure and fully understand the structure-property relationships. |
WOS记录号 | WOS:000589516000001 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7694] |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Pan, SL (Pan, Shilie)[ 1,2 ] |
作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelectron Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, CAS Key Lab Funct Mat & Devices Special Environme, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, CM ,Zhang, FF ,Cheng, SC ,et al. Ba-3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High-Temperature Solution Method[J]. CHEMISTRY-A EUROPEAN JOURNAL,2020,26(70):16628-16632. |
APA | Huang, CM ,Zhang, FF ,Cheng, SC ,Yang, ZH ,Li, H ,&Pan, SL .(2020).Ba-3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High-Temperature Solution Method.CHEMISTRY-A EUROPEAN JOURNAL,26(70),16628-16632. |
MLA | Huang, CM ,et al."Ba-3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High-Temperature Solution Method".CHEMISTRY-A EUROPEAN JOURNAL 26.70(2020):16628-16632. |
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