Two Lanthanide Borate Chlorides LnB(4)O(6)(OH)(2)Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses | |
Guo, FJ (Guo, Fengjiao)[ 1,2,3 ]; Han, J (Han, Jian)[ 1,2 ]; Cheng, JN (Cheng, Jianian)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ]; Mutailipu, M (Mutailipu, Miriding)[ 1,2,3 ]; Pan, SL (Pan, Shilie)[ 1,2 ] | |
刊名 | INORGANIC CHEMISTRY
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2018 | |
卷号 | 57期号:23页码:14953-14960 |
ISSN号 | 0020-1669 |
DOI | 10.1021/acs.inorgchem.8b02778 |
英文摘要 | Two borate chlorides LaB4O6(OH)(2)Cl and Ce-B4O6(OH)(2)Cl have been synthesized and characterized. Both of them exhibit structure similar to that of notable KBe2BO3F2 and feature two-dimensional [B4O6(OH)(2)](infinity) layers constructed by [B4O8(OH)](2) fundamental building blocks. Thermal analyses, infrared spectroscopy, UV-vis-NIR spectra, and second harmonic generation measurement were performed to investigate their physical properties. The results show that both of them have high decomposition temperatures and large second-harmonic generation responses (2.3 and 2.1 x KH2PO4, respectively), and LaB4O6(OH)(2)Cl possesses a deep-UV cutoff edge below 180 nm and large band gap. Moreover, the first-principle calculations were carried out to clarify the role of the electronic structure in determining the associated optical properties of LaB4O6(OH)(2)Cl. These results demonstrate that LaB4O6(OH)(2)Cl can be considered as a candidate for ultraviolet nonlinear optical material. |
WOS记录号 | WOS:000452344400056 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7320] ![]() |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Pan, SL (Pan, Shilie)[ 1,2 ] |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, FJ ,Han, J ,Cheng, JN ,et al. Two Lanthanide Borate Chlorides LnB(4)O(6)(OH)(2)Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses[J]. INORGANIC CHEMISTRY,2018,57(23):14953-14960. |
APA | Guo, FJ ,Han, J ,Cheng, JN ,Yang, ZH ,Mutailipu, M ,&Pan, SL .(2018).Two Lanthanide Borate Chlorides LnB(4)O(6)(OH)(2)Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses.INORGANIC CHEMISTRY,57(23),14953-14960. |
MLA | Guo, FJ ,et al."Two Lanthanide Borate Chlorides LnB(4)O(6)(OH)(2)Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses".INORGANIC CHEMISTRY 57.23(2018):14953-14960. |
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