Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit

doi:10.1016/j.jssc.2012.01.061

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 材料物理与化学研究室

	Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit
	Zhang Min; Pan Shilie; Han Jian; Yang Zhihua; Su Xin; Zhao Wenwu
刊名	Journal of Solid State Chemistry
	2012
卷号	190 期号:6 页码:92-97
关键词	Li2sr4b12o23 Crystal Structure Crystal Growth Borate
ISSN号	0022-4596
DOI	10.1016/j.jssc.2012.01.061
英文摘要	A novel ternary lithium strontium borate Li2Sr4B 12O23 crystal with size up to 20 mm×10 mm×4 mm has been grown via the top-seeded solution growth method below 730 °C. Single-crystal XRD analyses showed that Li2Sr4B 12O23 crystallizes in the monoclinic space group P2 1/c with a=6.4664(4) A˚, b=8.4878(4) A˚, c=15.3337(8) A˚, β=102.02(3)°, Z=2. The crystal structure is composed of [B10O18]^6- network and isolated [B 2O5]^4- unit. The IR spectrum further confirmed the presence of both BO3 and BO4 groups. TG-DSC and Transmission spectrum were reported. Band structures and density of states were calculated.
学科主题	Chemistry
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1402]
专题	新疆理化技术研究所_材料物理与化学研究室
通讯作者	Pan Shilie
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang Min,Pan Shilie,Han Jian,et al. Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit[J]. Journal of Solid State Chemistry,2012,190(6):92-97.
APA	Zhang Min,Pan Shilie,Han Jian,Yang Zhihua,Su Xin,&Zhao Wenwu.(2012).Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit.Journal of Solid State Chemistry,190(6),92-97.
MLA	Zhang Min,et al."Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit".Journal of Solid State Chemistry 190.6(2012):92-97.