chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters

doi:10.1002/cjoc.201300063

	chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters
	Zhu Tingshun; Xu Minghua
刊名	chinesejournalofchemistry
	2013
卷号	31 期号:3 页码:321
关键词	ARYL BORONIC ACIDS ALPHA-KETOESTERS ALPHA,BETA-UNSATURATED KETONES ENANTIOSELECTIVE 1,2-ADDITION ADDITION-REACTIONS HYDROXYLATION ALDEHYDES PALLADACYCLES 1,2-DIKETONES 1,4-ADDITION asymmetric catalysis rhodium sulfur-olefin ligand 1 2-addition stereoselectivity reversal
ISSN号	1001-604X
DOI	10.1002/cjoc.201300063
英文摘要	Simple and readily available chiral N-(sulfinyl)allylamines have been developed as efficient novel ligands for the rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to challenging aliphatic -ketoesters. By employing the linear or branched sulfinamide-olefin ligands, interesting enantioselectivity as well as regioselectivity reversal in the related asymmetric additions were observed.
资助项目	[National Natural Science Foundation of China]
语种	英语
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/288362]
专题	中国科学院上海药物研究所
作者单位	中国科学院上海药物研究所
推荐引用方式 GB/T 7714	Zhu Tingshun,Xu Minghua. chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters[J]. chinesejournalofchemistry,2013,31(3):321.
APA	Zhu Tingshun,&Xu Minghua.(2013).chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters.chinesejournalofchemistry,31(3),321.
MLA	Zhu Tingshun,et al."chiralsulfinamideolefinligandsswitchableselectivityinrhodiumcatalyzedasymmetric12additionofarylboronicacidstoaliphaticketoesters".chinesejournalofchemistry 31.3(2013):321.