金属催化的碳杂键对炔键的加成反应研究进展

doi:10.6023/cjoc201607035

	金属催化的碳杂键对炔键的加成反应研究进展
	赵飞 1; 贾秀稳 1; 王东萍 1; 费朝丽 1; 吴成林 2; 王江 2; 柳红 2
刊名	有机化学
	2017
卷号	37 期号:2 页码:284
关键词	C-N BOND INTRAMOLECULAR TRANS-VINYLSILYLATION TERMINAL ALKYNES UNACTIVATED ALKYNES ACID-CHLORIDES REGIOSELECTIVE CYANOTHIOLATION 2,3-DISUBSTITUTED BENZOFURANS CYCLOISOMERIZATION REACTION STEREOSELECTIVE-SYNTHESIS CONVENIENT SYNTHESIS metal-catalyzed carbon-hetero bonds alkynes addition reactions
ISSN号	0253-2786
DOI	10.6023/cjoc201607035
英文摘要	The addition of carbon-hetero bonds to alkynes has become an important apporach for the functionalization of carbon-carbon triple bonds. It can construct two bonds, namely one carbon-carbon bond and one carbon-hetero bond, in a single one step. These addition reactions feature high efficiency and high atom-economy. In recent years, metal-catalyzed (Al, Fe, Ni, Cu, Ga, Ru, Rh, Pd, Hf, Ir, Pt, Au, Bi, etc.) addition of many various kinds of carbon-hetero bonds to alkynes has achieved lots of important developments. According to the types of carbon-hetero bonds, the addition of 8 different kinds of carbon-hetero bonds C-H, C-B, C-N, C-O, C-Si, C-S, C-X (X=Cl, Br, I), C-Se to alkynes is reviewed in this paper, and the reaction conditions, reaction selectivities (regioselectivities and stereoselectivities) and reaction mechanisms are also discussed and summarized.
资助项目	[National Natural Science Foundation of China] ; [Open Project Program of Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province]
语种	英语
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/286702]
专题	中国科学院上海药物研究所
作者单位	1.成都学院 2.中国科学院上海药物研究所
推荐引用方式 GB/T 7714	赵飞,贾秀稳,王东萍,等. 金属催化的碳杂键对炔键的加成反应研究进展[J]. 有机化学,2017,37(2):284.
APA	赵飞.,贾秀稳.,王东萍.,费朝丽.,吴成林.,...&柳红.(2017).金属催化的碳杂键对炔键的加成反应研究进展.有机化学,37(2),284.
MLA	赵飞,et al."金属催化的碳杂键对炔键的加成反应研究进展".有机化学 37.2(2017):284.