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Study on corrosion behavior of low carbon steel under different water conditions in bentonite of China-Mock-Up
Wei, Xin2; Liu, Yuemiao1; Dong, Junhua2; Cao, Shengfei1; Xie, Jingli1; Chen, Nan2; Xue, Fang2; Wang, Changgang2; Ke, Wei2
刊名APPLIED CLAY SCIENCE
2019
卷号167页码:23-32
关键词Waste disposal Corrosion behavior Low carbon steel Bentonite Water condition EIS
ISSN号0169-1317
DOI10.1016/j.clay.2018.10.004
通讯作者Dong, Junhua(jhdong@imr.ac.cn)
英文摘要In China-Mock-Up, the transition of water conditions in bentonite and its influence on the corrosion behavior of four low carbon steel electrochemical sensors buried in bentonite along horizontal direction were investigated by in situ electrochemical impedance spectroscopy (EIS) with the infiltration of groundwater from outside to inside. The results show that in the initial stage of EIS measurement, water in bentonite around the electrochemical sensors from outside to inside is hygroscopic water and chemical bonding water successively. With increasing time, water in the outer bentonite transforms from hygroscopic water to free water. Meanwhile, water in the inner bentonite transforms from chemical bonding water to hygroscopic water. As water in bentonite exists as the chemical bonding water, the equivalent circuit can be described as a pure capacitor, which does not cause the corrosion of low carbon steel. When water in bentonite exists as hygroscopic water, it can be described as a circuit consisting of two leakage capacitors in series, which causes the slight corrosion of the steel. While, in the presence of free water, the equivalent circuit can be described as a free water resistance and two leakage capacitors in series, which causes the serious corrosion of the steel.
资助项目National Natural Science Foundation of China[51471175] ; National Natural Science Foundation of China[51701222]
WOS研究方向Chemistry ; Materials Science ; Mineralogy
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000449900400003
资助机构National Natural Science Foundation of China
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/130211]  
专题金属研究所_中国科学院金属研究所
通讯作者Dong, Junhua
作者单位1.Res Inst Uranium Geol, Beijing 100029, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Wei, Xin,Liu, Yuemiao,Dong, Junhua,et al. Study on corrosion behavior of low carbon steel under different water conditions in bentonite of China-Mock-Up[J]. APPLIED CLAY SCIENCE,2019,167:23-32.
APA Wei, Xin.,Liu, Yuemiao.,Dong, Junhua.,Cao, Shengfei.,Xie, Jingli.,...&Ke, Wei.(2019).Study on corrosion behavior of low carbon steel under different water conditions in bentonite of China-Mock-Up.APPLIED CLAY SCIENCE,167,23-32.
MLA Wei, Xin,et al."Study on corrosion behavior of low carbon steel under different water conditions in bentonite of China-Mock-Up".APPLIED CLAY SCIENCE 167(2019):23-32.
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