The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability

doi:10.1002/adfm.201801737

CORC > 金属研究所 > 中国科学院金属研究所

	The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability
	Tian, Hao 6,7; Huang, Fei 8; Zhu, Yihan 1,2; Liu, Shaomin 7; Han, Yu 1; Jaroniec, Mietek 3; Yang, Qihua 6; Liu, Hongyang 8; Lu, Gao Qing Max 5; Liu, Jian 4,6,7
刊名	ADVANCED FUNCTIONAL MATERIALS
	2018-08-08
卷号	28 期号:32 页码:10
关键词	metal-organic frameworks phenylacetylene hydrogenation submicroreactors yolk-shell particles zeolite imidazolate frameworks
ISSN号	1616-301X
DOI	10.1002/adfm.201801737
通讯作者	Liu, Hongyang(liuhy@imr.ac.cn) ; Liu, Jian(jianliu@dicp.ac.cn)
英文摘要	Design of multicomponent yolk-shell structures is crucial for the fabrication of micro/nanoreactors for a variety of applications. This work reports the rational design and synthesis of yolk-shell-structured submicroreactors with loaded metal nanoparticles into ZnO-microporous carbon core-shell structures. The solvothermal treatment and carbonization process of uniform zeolitic imidazolate framework-8 (ZIF-8)@resin polymer core-shell structures leads to the generation of yolk-shell-structured ZnO@carbon. The synthesis conditions are optimized to track the evolution of ZIF-8 in a confined space of resin polymer as a submicroreactor itself. It is found that nanoribbon evolution occurs via the formation of the intermediate needle-like particles. The Pd&ZnO@carbon submicroreactor is shown to be a highly selective catalyst (selectivity >99%) for hydrogenation of phenylacetylene to phenylethylene. The excellent performance of Pd&ZnO@carbon particles is evidenced by higher conversion and selectivity than that of Pd/ZnO and Pd/C with similar Pd loading. Furthermore, Pd&ZnO@carbon submicroreactors show superior catalytic stability, and no deactivation after 25 h of reaction. The proposed strategy is promising for the design of multifunctional micro/nanoreactors or nanocontainers for construction of artificial cells.
资助项目	Australian Research Council (ARC)[DP180100568] ; Australian Research Council (ARC)[LP150101158] ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology[2016YFA0204100] ; National Natural Science Foundation of China[21573254] ; National Natural Science Foundation of China[91545110] ; Youth Innovation Promotion Association(CAS) ; Sinopec China
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000440810500010
资助机构	Australian Research Council (ARC) ; Chinese Government 1000 young talent plan ; Curtin Strategic International Research Scholarship ; Curtin University Mobility Scholarship ; Chinese Government Award for Outstanding Self-Financed Students Abroad ; Ministry of Science and Technology ; National Natural Science Foundation of China ; Youth Innovation Promotion Association(CAS) ; Sinopec China
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/128889]
专题	金属研究所_中国科学院金属研究所
通讯作者	Liu, Hongyang; Liu, Jian
作者单位	1.King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia 2.Zhejiang Univ Technol, Dept Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China 3.Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA 4.Univ Surrey, Dept Chem & Proc Engn, Guildford GU2 7XH, Surrey, England 5.Univ Surrey, Vice Chancellors Off, Guildford GU2 7XH, Surrey, England 6.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 7.Curtin Univ, Dept Chem Engn, Perth, WA 6845, Australia 8.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Tian, Hao,Huang, Fei,Zhu, Yihan,et al. The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability[J]. ADVANCED FUNCTIONAL MATERIALS,2018,28(32):10.
APA	Tian, Hao.,Huang, Fei.,Zhu, Yihan.,Liu, Shaomin.,Han, Yu.,...&Liu, Jian.(2018).The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability.ADVANCED FUNCTIONAL MATERIALS,28(32),10.
MLA	Tian, Hao,et al."The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability".ADVANCED FUNCTIONAL MATERIALS 28.32(2018):10.