Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O)

doi:10.1088/0256-307X/28/6/067105

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	Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O)
	Li Ju-Fen 2; Kuang Xiao-Yu 1,3
刊名	CHINESE PHYSICS LETTERS
	2011-06-01
卷号	28 期号:6 页码:3
ISSN号	0256-307X
DOI	10.1088/0256-307X/28/6/067105
通讯作者	Li Ju-Fen()
英文摘要	The electron paramagnetic resonance spectra of trigonal Mn2+ centers in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O) crystals are studied on the basis of the complete energy matrices for a d(5) configuration ion in a trigonal ligand field. It is demonstrated that the local lattice structure around a trigonal Mn2+ center has an elongation distortion along the crystalline c(3) axis, and when Mn2+ is doped in the ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O) crystals, there is a similar local distortion. From the EPR calculation, the local lattice structure parameters for trigonal Mn2+ centers in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O) are determined.
资助项目	National Natural Science Foundation[10374068] ; Specialized Research Fund for the Doctoral Program of Higher Education of China[20050610011]
WOS研究方向	Physics
语种	英语
出版者	IOP PUBLISHING LTD
WOS记录号	WOS:000291243400063
资助机构	National Natural Science Foundation ; Specialized Research Fund for the Doctoral Program of Higher Education of China
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/106215]
专题	金属研究所_中国科学院金属研究所
通讯作者	Li Ju-Fen
作者单位	1.Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China 2.SW Petr Univ, Sch Sci, Chengdu 610065, Peoples R China 3.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Li Ju-Fen,Kuang Xiao-Yu. Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O)[J]. CHINESE PHYSICS LETTERS,2011,28(6):3.
APA	Li Ju-Fen,&Kuang Xiao-Yu.(2011).Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O).CHINESE PHYSICS LETTERS,28(6),3.
MLA	Li Ju-Fen,et al."Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5 center dot 6(H2O) and CoNbOF5 center dot 6(H2O)".CHINESE PHYSICS LETTERS 28.6(2011):3.