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Fabrication and performance of membrane solid oxide fuel cells with La0.75Sr0.25Cr0.5Mn0.5O3-delta impregnated anodes
Zhu, Xingbao1; Zhe Lue1; Bo Wei1; Chen, Kongfa1; Liu, Mingliang1; Huang, Xiqiang1; Su, Wenhui1,2
刊名JOURNAL OF POWER SOURCES
2010-04-02
卷号195期号:7页码:1793-1798
关键词Solid oxide fuel cells Perovskite oxide LSCrM Wet impregnation Porous anode
ISSN号0378-7753
DOI10.1016/j.jpowsour.2009.10.042
通讯作者Zhu, Xingbao(zhuxingbao008@163.com)
英文摘要La0.75Sr0.25Cr0.5Mn0.5O3-delta (LSCrM)-impregnated anodes have been fabricated by infiltrating 70% porous yttria-stabilized zirconia (YSZ) matrixes with an LSCrM solution. In these anodes, LSCrM is a primary electronic conducive phase while the well-sintered YSZ provides an ionic-conducting pathway throughout the electrode. The maximum power densities of a single cell with YSZ+35wt.% LSCrM composite anode reach 567 and 561 mW cm(-2) at 850 degrees C in dry H-2 and CH4, respectively. Further, Ag and Ni are added via nitrate impregnating method for improving electronic conductivity and catalytic activity. With the addition of 6wt.%Ni and 2wt.% Ag to the YSZ+32wt.% LSCrM composite anode, the maximum power densities at 850 degrees C increase to 1302 mWcm(-2) in dry H-2 and 769mWcm(-2) in dry CH4. No carbon deposition is detected in the tested anodes, even with the presence of Ni. (C) 2009 Elsevier B.V. All rights reserved.
资助项目Ministry of Science and Technology of China[2007AA05Z139]
WOS研究方向Electrochemistry ; Energy & Fuels
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000273883400005
资助机构Ministry of Science and Technology of China
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/102924]  
专题金属研究所_中国科学院金属研究所
通讯作者Zhu, Xingbao
作者单位1.Harbin Inst Technol, Dept Phys, Ctr Condensed Matter Sci & Technol, Harbin 150080, Peoples R China
2.Int Ctr Mat Phys, Shenyang 110015, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Xingbao,Zhe Lue,Bo Wei,et al. Fabrication and performance of membrane solid oxide fuel cells with La0.75Sr0.25Cr0.5Mn0.5O3-delta impregnated anodes[J]. JOURNAL OF POWER SOURCES,2010,195(7):1793-1798.
APA Zhu, Xingbao.,Zhe Lue.,Bo Wei.,Chen, Kongfa.,Liu, Mingliang.,...&Su, Wenhui.(2010).Fabrication and performance of membrane solid oxide fuel cells with La0.75Sr0.25Cr0.5Mn0.5O3-delta impregnated anodes.JOURNAL OF POWER SOURCES,195(7),1793-1798.
MLA Zhu, Xingbao,et al."Fabrication and performance of membrane solid oxide fuel cells with La0.75Sr0.25Cr0.5Mn0.5O3-delta impregnated anodes".JOURNAL OF POWER SOURCES 195.7(2010):1793-1798.
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