Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3 | |
Zhang, Xingquan1; Sui, Yu1,2; Wang, Xianjie1; Wang, Yang3; Wang, Zhu1 | |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS |
2010-09-24 | |
卷号 | 507期号:1页码:157-161 |
关键词 | Multiferroic BiFeO3 Substitution Magnetoelectric coupling |
ISSN号 | 0925-8388 |
DOI | 10.1016/j.jallcom.2010.07.144 |
通讯作者 | Sui, Yu(suiyu@hit.edu.cn) |
英文摘要 | Single-phase Bil(1-x)Eu(x)FeO(3) (0 <= x <= 0.3) multiferroic ceramics were prepared to study the effects of Eu substitution on their crystal structure and ferroelectromagnetic behavior. X-ray diffraction studies revealed a sequence of the composition-driven structural phase transitions R3c -> Pn2(1)alpha (occurs at x = 0.2). Magnetic measurements revealed that Eu substitution can effectively induce the appearance of the spontaneous magnetization, which was significantly enhanced upon the composition-driven transition from a rhombohedral to an orthorhombic phase. The leakage current was found to be reduced on increased Eu concentration. The electric hysteresis loops were obtained in the Bi1-xEuxFeO3 ceramics, but the loops were not really saturated. The magnetoelectric coupling in Eu-doped BiFeO3 was estimated by the changes in the dielectric constant with an external magnetic filed. (C) 2010 Elsevier B.V. All rights reserved. |
资助项目 | National Natural Science Foundation of China[50672019] ; National Natural Science Foundation of China[10804024] ; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry ; natural scientific research innovation foundation in Harbin Institute of Technology[HIT. NSRIF.2009056] |
WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000283005300034 |
资助机构 | National Natural Science Foundation of China ; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry ; natural scientific research innovation foundation in Harbin Institute of Technology |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/100754] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Sui, Yu |
作者单位 | 1.Harbin Inst Technol, Ctr Condensed Matter Sci & Technol, Dept Phys, Harbin 150001, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China 3.Nanyang Technol Univ, Div Phys & Appl Phys, Sch Phys & Math Sci, Singapore 637371, Singapore |
推荐引用方式 GB/T 7714 | Zhang, Xingquan,Sui, Yu,Wang, Xianjie,et al. Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2010,507(1):157-161. |
APA | Zhang, Xingquan,Sui, Yu,Wang, Xianjie,Wang, Yang,&Wang, Zhu.(2010).Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3.JOURNAL OF ALLOYS AND COMPOUNDS,507(1),157-161. |
MLA | Zhang, Xingquan,et al."Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO3".JOURNAL OF ALLOYS AND COMPOUNDS 507.1(2010):157-161. |
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