Enhanced Photoactivity of Oxygen-Deficient Anatase TiO2 Sheets with Dominant {001} Facets

doi:10.1021/jp907749r

CORC > 金属研究所 > 中国科学院金属研究所

	Enhanced Photoactivity of Oxygen-Deficient Anatase TiO2 Sheets with Dominant {001} Facets
	Liu, Gang 1,2,3; Yang, Hua Gui 4; Wang, Xuewen 3; Cheng, Lina 1,2; Lu, Haofeng 3; Wang, Lianzhou 1,2; Lu, Gao Qing (Max)1,2; Cheng, Hui-Ming 3
刊名	JOURNAL OF PHYSICAL CHEMISTRY C
	2009-12-31
卷号	113 期号:52 页码:21784-21788
ISSN号	1932-7447
DOI	10.1021/jp907749r
通讯作者	Lu, Gao Qing (Max)(maxlu@uq.edu.au)
英文摘要	Constructing photocatalytically favorable Surface structure in synthesizing photocatalysts plays an important role in enhancing the photocatalytic activity of semiconductor photocatalysts. In this report, oxygen-deficient anatase TiO2 sheets with dominant {001} facets were synthesized via a facile one-pot hydrothermal route with solid metallic titanium diboride as precursor. In contrast to anatase TiO2 sheets with dominant {001} facets free of oxygen deficiency and surface fluorine, anatase TiO2 sheets with oxygen deficiency and surface fluorine are Subject to obvious surface reconstruction as evidenced by two new Raman-active modes at 155 and 171 cm(-1) and the weakened B-1g mode at 397 cm(-1). Further analysis based on X-ray photoelectron spectroscopy (XPS) spectra of Pt 4f and F Is provided a clear evidence for the greatly strengthened interaction between Pt-loaded and TiO2 matrix as a result of a special electron-transfer process on the reconstructed Surface structure of TiO2 with both oxygen deficiency and fluorine. Importantly, the reconstructed surface structure as well as the strengthened interaction between Pt-loaded and TiO2 matrix can substantially enhance the hydrogen evolution rate from photocatalytic water splitting reactions.
资助项目	Ministry of Science and Technology of China[2009CB220001] ; NSFC[50921004] ; Solar Energy Program of the Chinese Academy of Sciences ; IMR SYNL-T.S. KC Research Fellowship ; Australian Research Council[DP0666345] ; Pujiang Talents Program of Science and Technology Commission of Shanghai Municipality[09PJ1402800] ; [KJCX2-YW-H21-01]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000272936400045
资助机构	Ministry of Science and Technology of China ; NSFC ; Solar Energy Program of the Chinese Academy of Sciences ; IMR SYNL-T.S. KC Research Fellowship ; Australian Research Council ; Pujiang Talents Program of Science and Technology Commission of Shanghai Municipality
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/97741]
专题	金属研究所_中国科学院金属研究所
通讯作者	Lu, Gao Qing (Max)
作者单位	1.Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia 2.Univ Queensland, Sch Engn, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China
推荐引用方式 GB/T 7714	Liu, Gang,Yang, Hua Gui,Wang, Xuewen,et al. Enhanced Photoactivity of Oxygen-Deficient Anatase TiO2 Sheets with Dominant {001} Facets[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2009,113(52):21784-21788.
APA	Liu, Gang.,Yang, Hua Gui.,Wang, Xuewen.,Cheng, Lina.,Lu, Haofeng.,...&Cheng, Hui-Ming.(2009).Enhanced Photoactivity of Oxygen-Deficient Anatase TiO2 Sheets with Dominant {001} Facets.JOURNAL OF PHYSICAL CHEMISTRY C,113(52),21784-21788.
MLA	Liu, Gang,et al."Enhanced Photoactivity of Oxygen-Deficient Anatase TiO2 Sheets with Dominant {001} Facets".JOURNAL OF PHYSICAL CHEMISTRY C 113.52(2009):21784-21788.