Hollow mesoporous silica materials with well-ordered cubic Ia3d mesostructured shell for toluene adsorption | |
Qiao, Nanli; He, Chi; Zhang, Xin; Yang, Hongling; Cheng, Jie; Hao, Zhengping | |
刊名 | JOURNAL OF POROUS MATERIALS |
2019-02-01 | |
卷号 | 26期号:1页码:59-68 |
关键词 | Hollow structure Ordered mesoporous silica Toluene Absorbent |
ISSN号 | 1380-2224 |
英文摘要 | In this work, hollow mesoporous silica samples (HMSs) with uniform diameter (approximate to 400 nm), high specific surface area (1138-1742 m(2)/g) and stable structure were successfully synthesized. The shell of synthesized HMSs displays the well-ordered cubic Ia3d mesostructure with uniform mesopores of ca. 2.7 nm, and the shell thickness is easily adjusted in range from 30 to 80 nm. More importantly, the potential applications of HMSs are further demonstrated for adsorption capacity, toluene as the model molecule. HMSs exhibit remarkably higher adsorption capacity, especially HMS-3. The saturated adsorption amount toward toluene of HMS-3 can reach as high as 5.93 mmol/g that is almost two times larger than that of MCM-48 (2.74 mmol/g). In addition, Henry constants and adsorption kinetics date on HMS-3 and MCM-48 for toluene were also evaluated in detail. By a contrastive analysis, the good sorption capacity of HMS-3 for toluene could be ascribed to the unique interior voids and strong adsorption energy with each other. |
内容类型 | 期刊论文 |
源URL | [http://ir.rcees.ac.cn/handle/311016/43195] |
专题 | 生态环境研究中心_环境纳米材料实验室 |
作者单位 | 1.Beijng Inst Petrochem Technol, Dept Chem Engn, Beijing 102617, Peoples R China 2.Chinese Acad Sci, Dept Environm Nanomat, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China 3.Xi An Jiao Tong Univ, Sch Energy & Power Engn, Dept Environm Sci & Engn, Xian 710049, Shaanxi, Peoples R China |
推荐引用方式 GB/T 7714 | Qiao, Nanli,He, Chi,Zhang, Xin,et al. Hollow mesoporous silica materials with well-ordered cubic Ia3d mesostructured shell for toluene adsorption[J]. JOURNAL OF POROUS MATERIALS,2019,26(1):59-68. |
APA | Qiao, Nanli,He, Chi,Zhang, Xin,Yang, Hongling,Cheng, Jie,&Hao, Zhengping.(2019).Hollow mesoporous silica materials with well-ordered cubic Ia3d mesostructured shell for toluene adsorption.JOURNAL OF POROUS MATERIALS,26(1),59-68. |
MLA | Qiao, Nanli,et al."Hollow mesoporous silica materials with well-ordered cubic Ia3d mesostructured shell for toluene adsorption".JOURNAL OF POROUS MATERIALS 26.1(2019):59-68. |
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