Photoelectrochemical cathodic protection of Cu2O/TiO2 p-n heterojunction under visible light
Tian, Jing1,2,4; Chen, Zhuoyuan2,4; Jing, Jiangping4; Feng, Chang1,4; Sun, Mengmeng4; Li, Weibing3
刊名JOURNAL OF OCEANOLOGY AND LIMNOLOGY
2020-06-07
页码15
关键词Cu2O TiO2 p-n heterojunction 316L SS photoelectrochemical cathodic protection
ISSN号2096-5508
DOI10.1007/s00343-020-9327-y
通讯作者Chen, Zhuoyuan(zychen@qdio.ac.cn)
英文摘要The Cu2O/TiO2 p-n heterojunction composite photoelectrodes were prepared by depositing Cu2O nanoparticles on the surface of TiO2 nanotubes via anodic oxidation and constant current deposition. Field emission scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) analyses showed that Cu2O nanoparticles not only deposited on the surface of TiO2 nanotube array, but also on the wall of TiO2 nanotubes. The Cu2O deposition amount could be adjusted by changing the deposition time. The photoelectrochemical cathodic protection (PECCP) performance of the prepared photoelectrodes for 316L stainless steel (SS) was tested under visible light. The constant current deposition time had a significant effect on the PECCP performance of Cu2O/TiO2-X photoelectrodes and Cu2O/TiO2-20 had the best PECCP performance for the coupled 316L SS. This was attributed to the appropriate amount and thickness of Cu2O to form p-n heterojunctions with TiO2, in which separation of the photogenerated carriers was accelerated and transfer of the photogenerated electrons to 316L SS for PECCP was facilitated.
资助项目National Natural Science Foundation of China[41576114] ; National Natural Science Foundation of China[41676069] ; State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, China[614290101011703] ; Qingdao Innovative Leading Talent Foundation[15-10-3-15-(39)-zch]
WOS研究方向Marine & Freshwater Biology ; Oceanography
语种英语
出版者SCIENCE PRESS
WOS记录号WOS:000538973700004
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/167699]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Chen, Zhuoyuan
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Peoples R China
3.Qingdao Univ Sci & Technol, Sch Environm & Safety Engn, Qingdao 266042, Peoples R China
4.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
推荐引用方式
GB/T 7714
Tian, Jing,Chen, Zhuoyuan,Jing, Jiangping,et al. Photoelectrochemical cathodic protection of Cu2O/TiO2 p-n heterojunction under visible light[J]. JOURNAL OF OCEANOLOGY AND LIMNOLOGY,2020:15.
APA Tian, Jing,Chen, Zhuoyuan,Jing, Jiangping,Feng, Chang,Sun, Mengmeng,&Li, Weibing.(2020).Photoelectrochemical cathodic protection of Cu2O/TiO2 p-n heterojunction under visible light.JOURNAL OF OCEANOLOGY AND LIMNOLOGY,15.
MLA Tian, Jing,et al."Photoelectrochemical cathodic protection of Cu2O/TiO2 p-n heterojunction under visible light".JOURNAL OF OCEANOLOGY AND LIMNOLOGY (2020):15.
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