High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol | |
Dong, Min2; Zhang, Kewei2; Wang, Lili2; Han, Jie2; Wang, Yingxia1; Xue, Zhixin2; Xia, Yanzhi2 | |
刊名 | CARBOHYDRATE POLYMERS
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2020-05-15 | |
卷号 | 236页码:8 |
关键词 | Carrageenan fibers Ba2+ Spinning solution High-strength |
ISSN号 | 0144-8617 |
DOI | 10.1016/j.carbpol.2020.116057 |
通讯作者 | Xue, Zhixin(xuezhixin@qdu.edu.cn) |
英文摘要 | Carrageenan fibers have attractive applications in textile, but their low strength remains a problem that needs to be urgently addressed. In this work, a novel facile, environmental friendly method for fabricate high-strength carrageenan fibers is proposed. It involves the crosslinking of a small amount of Ba2+ ions in the carrageenan solution, followed by using recyclable alcohol in coagulation and stretching baths. Carrageenan molecular chains were allowed to first sufficiently interact with metal barium ions, and then were stretched and dehydrated with alcohol to increase the hydrogen bonding interaction between the molecular chains. As a result, the carrageenan fibers with high-strength ionic and hydrogen bonds were obtained. The fibers obtained by the novel method had high tensile strength at 1.63 cN/dtex, which is two times higher than that of those obtained by the traditional process. |
资助项目 | National High Technology Research and Development Program of China[2010AA093701] ; National Natural Science Foundation of China[50803030] ; National Natural Science Foundation of China[51973099] ; Program for Chang jiang Scholars and Innovative Research Team in University[IRT0970] ; Postdoctoral Science Special Foundation of China[201104581] ; Postdoctoral Science Foundation of China[20100471495] ; Program for Excellent Innovative Research Team of Shandong Province, China[TD200902] ; Natural Science Foundation of Shandong Province, China[ZR2016EMB21] ; Taishan Scholar Program of Shandong Province |
WOS研究方向 | Chemistry ; Polymer Science |
语种 | 英语 |
出版者 | ELSEVIER SCI LTD |
WOS记录号 | WOS:000519306900041 |
内容类型 | 期刊论文 |
源URL | [http://ir.qdio.ac.cn/handle/337002/165849] ![]() |
专题 | 中国科学院海洋研究所 |
通讯作者 | Xue, Zhixin |
作者单位 | 1.Chinese Acad Sci, Publ Technol Serv Ctr, Inst Oceanol, Qingdao 266071, Peoples R China 2.Qingdao Univ, Collaborat Innovat Ctr Marine Biobased Fibers & c, State Key Lab Biofibers & Ecotext, Inst Marine Biobased Mat,Coll Chem & Chem Engn, Qingdao 266071, Peoples R China |
推荐引用方式 GB/T 7714 | Dong, Min,Zhang, Kewei,Wang, Lili,et al. High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol[J]. CARBOHYDRATE POLYMERS,2020,236:8. |
APA | Dong, Min.,Zhang, Kewei.,Wang, Lili.,Han, Jie.,Wang, Yingxia.,...&Xia, Yanzhi.(2020).High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol.CARBOHYDRATE POLYMERS,236,8. |
MLA | Dong, Min,et al."High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol".CARBOHYDRATE POLYMERS 236(2020):8. |
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