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High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol
Dong, Min2; Zhang, Kewei2; Wang, Lili2; Han, Jie2; Wang, Yingxia1; Xue, Zhixin2; Xia, Yanzhi2
刊名CARBOHYDRATE POLYMERS
2020-05-15
卷号236页码:8
关键词Carrageenan fibers Ba2+ Spinning solution High-strength
ISSN号0144-8617
DOI10.1016/j.carbpol.2020.116057
通讯作者Xue, Zhixin(xuezhixin@qdu.edu.cn)
英文摘要Carrageenan fibers have attractive applications in textile, but their low strength remains a problem that needs to be urgently addressed. In this work, a novel facile, environmental friendly method for fabricate high-strength carrageenan fibers is proposed. It involves the crosslinking of a small amount of Ba2+ ions in the carrageenan solution, followed by using recyclable alcohol in coagulation and stretching baths. Carrageenan molecular chains were allowed to first sufficiently interact with metal barium ions, and then were stretched and dehydrated with alcohol to increase the hydrogen bonding interaction between the molecular chains. As a result, the carrageenan fibers with high-strength ionic and hydrogen bonds were obtained. The fibers obtained by the novel method had high tensile strength at 1.63 cN/dtex, which is two times higher than that of those obtained by the traditional process.
资助项目National High Technology Research and Development Program of China[2010AA093701] ; National Natural Science Foundation of China[50803030] ; National Natural Science Foundation of China[51973099] ; Program for Chang jiang Scholars and Innovative Research Team in University[IRT0970] ; Postdoctoral Science Special Foundation of China[201104581] ; Postdoctoral Science Foundation of China[20100471495] ; Program for Excellent Innovative Research Team of Shandong Province, China[TD200902] ; Natural Science Foundation of Shandong Province, China[ZR2016EMB21] ; Taishan Scholar Program of Shandong Province
WOS研究方向Chemistry ; Polymer Science
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000519306900041
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/165849]  
专题中国科学院海洋研究所
通讯作者Xue, Zhixin
作者单位1.Chinese Acad Sci, Publ Technol Serv Ctr, Inst Oceanol, Qingdao 266071, Peoples R China
2.Qingdao Univ, Collaborat Innovat Ctr Marine Biobased Fibers & c, State Key Lab Biofibers & Ecotext, Inst Marine Biobased Mat,Coll Chem & Chem Engn, Qingdao 266071, Peoples R China
推荐引用方式
GB/T 7714
Dong, Min,Zhang, Kewei,Wang, Lili,et al. High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol[J]. CARBOHYDRATE POLYMERS,2020,236:8.
APA Dong, Min.,Zhang, Kewei.,Wang, Lili.,Han, Jie.,Wang, Yingxia.,...&Xia, Yanzhi.(2020).High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol.CARBOHYDRATE POLYMERS,236,8.
MLA Dong, Min,et al."High-strength carrageenan fibers with compactly packed chain structure induced by combination of Ba2+ and ethanol".CARBOHYDRATE POLYMERS 236(2020):8.
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