Flexible Ethylene Propylene Diene Monomer/Paraffin Wax Vulcanizate with Simultaneously Increased Mechanical Strength, Thermal-Energy Storage, and Shape-Memory Behavior
Lu, Xiang; Yu, Hongwei; Zhang, Lihua; Zheng, Yongfeng; Xu, Linqiong; Zhao, Yongqing
刊名ENERGY & FUELS
2020
卷号34期号:7页码:9020-9029
关键词PHASE-CHANGE MATERIALS POLYETHYLENE-GLYCOL AEROGEL
DOI10.1021/acs.energyfuels.0c01800
英文摘要Various flexible ethylene propylene diene monomer (EPDM)/paraffin wax (PW) vulcanizates with simultaneously increased mechanical strength, thermal energy storage (TES), and shape-memory behavior were prepared via the general meltblending method. Herein, the PW served as a phase-change working substance for TES applications and as a "hard phase" for shape fixation, and the vulcanized EPDM acted as a supporting material to avoid the leakage of PW and as a "soft phase" for shape recovery. Under the action of the vulcanizing agent, the gel loading of the EPDM component in the EPDM/PW blends increased from 42.0 to 96.0%, and the denser cross-link density provided excellent mechanical strength for the EPDM/PW vulcanizate. The melting and freezing latent heat of the EPDM/PW blend with 60.0 wt % PW (C60) were 123.5 and 121.8 J/g, respectively, and the melting and freezing relative enthalpy efficiencies of C60 were as high as 99.5 and 99.2%, respectively. In addition, C60 has good thermal reliability after 100 thermal cycles, excellent light-to-thermal energy storage, and shape-memory behavior. This study provides a strategy to prepare flexible shape-stable phase-change materials (SSPCMs) via melt-blending for large-scale preparation, and these proposed SSPCMs have a very high commercial value.
学科主题Energy & Fuels ; Engineering
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/20646]  
专题2020专题
作者单位1.Zhao, YQ (corresponding author), Chinese Acad Sci, Ningbo Key Lab Polymer Mat, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China.
2.Lu, X (corresponding author), South China Univ Technol, Guangdong Key Lab Tech & Equipment Macromol Adv M, Natl Engn Res Ctr Novel Equipment Polymer Proc, Key Lab Polymer Proc Engn,Minist Educ, Guangzhou 510641, Peoples R China.
推荐引用方式
GB/T 7714
Lu, Xiang,Yu, Hongwei,Zhang, Lihua,et al. Flexible Ethylene Propylene Diene Monomer/Paraffin Wax Vulcanizate with Simultaneously Increased Mechanical Strength, Thermal-Energy Storage, and Shape-Memory Behavior[J]. ENERGY & FUELS,2020,34(7):9020-9029.
APA Lu, Xiang,Yu, Hongwei,Zhang, Lihua,Zheng, Yongfeng,Xu, Linqiong,&Zhao, Yongqing.(2020).Flexible Ethylene Propylene Diene Monomer/Paraffin Wax Vulcanizate with Simultaneously Increased Mechanical Strength, Thermal-Energy Storage, and Shape-Memory Behavior.ENERGY & FUELS,34(7),9020-9029.
MLA Lu, Xiang,et al."Flexible Ethylene Propylene Diene Monomer/Paraffin Wax Vulcanizate with Simultaneously Increased Mechanical Strength, Thermal-Energy Storage, and Shape-Memory Behavior".ENERGY & FUELS 34.7(2020):9020-9029.
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