Facile Preparation of Polyimine Vitrimers with Enhanced Creep Resistance and Thermal and Mechanical Properties via Metal Coordination

doi:10.1021/acs.macromol.0c00036

CORC > 宁波材料技术与工程研究所 > 中国科学院宁波材料技术与工程研究所 > 2020专题

	Facile Preparation of Polyimine Vitrimers with Enhanced Creep Resistance and Thermal and Mechanical Properties via Metal Coordination
	Wang, Sheng; Ma, Songqi; Li, Qong; Xu, Xiwei; Wang, Binbo; Huang, Kaifeng; Liu, Yanlin; Zhu, Jin
刊名	MACROMOLECULES
	2020
卷号	53 期号:8 页码:2919-2931
关键词	HIGHLY MALLEABLE THERMOSETS HIGH-PERFORMANCE DEGRADABLE THERMOSETS FLAME-RETARDANT DENSITY COMPLEXES VANILLIN NETWORKS EXCHANGE BONDS
DOI	10.1021/acs.macromol.0c00036
英文摘要	Vitrimers undergoing dynamic bond exchange enable reprocessing and recycle of thermosets. However, vitrimers are susceptible to creep, leading to their poor dimensional stability, which limits their applications. Here, a facile method via integration of metal complexes was utilized to address this issue, and cross-linked polyimine was selected as an example of vitrimer. Three different metal complexes were introduced into a polyimine vitrimer via a one-pot preparation involving the formation of metal complexes and crosslinking of polyimine. The addition of 0.5 mol % Cu2+ relative to imine bond reduced creep degree from 30% to 20% at 60 degrees C, and the creep resistance was enhanced with increasing Cu2+ content. Loading 5 mol % Cu2+ increased the initial creep temperature from 60 to about 100 degrees C and raised the Arrhenius activation energy (E-a) for stress relaxation from 52.3 to 67.7 kJ mol(-1). The ability of different metal complexes to suppress creep followed the order of Fe3+ > Cu2+ > Mg2+, and the initial creep temperature reached around 120 degrees C for vitrimer with 5 mol % of Fe3+. Meanwhile, the polyimine-metal complex vitrimers still exhibited excellent reprocessing recyclability. Moreover, the introduction of coordination structures enhanced the thermal and mechanical properties, solvent, and acid resistance. Thus, metal coordination is an efficient approach to achieve high-temperature creep resistance, excellent thermal and mechanical properties, and chemical stability for vitrimers based on the Schiff base.
学科主题	Polymer Science
内容类型	期刊论文
源URL	[http://ir.nimte.ac.cn/handle/174433/19761]
专题	2020专题
作者单位	Ma, SQ (corresponding author), Chinese Acad Sci, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China.
推荐引用方式 GB/T 7714	Wang, Sheng,Ma, Songqi,Li, Qong,et al. Facile Preparation of Polyimine Vitrimers with Enhanced Creep Resistance and Thermal and Mechanical Properties via Metal Coordination[J]. MACROMOLECULES,2020,53(8):2919-2931.
APA	Wang, Sheng.,Ma, Songqi.,Li, Qong.,Xu, Xiwei.,Wang, Binbo.,...&Zhu, Jin.(2020).Facile Preparation of Polyimine Vitrimers with Enhanced Creep Resistance and Thermal and Mechanical Properties via Metal Coordination.MACROMOLECULES,53(8),2919-2931.
MLA	Wang, Sheng,et al."Facile Preparation of Polyimine Vitrimers with Enhanced Creep Resistance and Thermal and Mechanical Properties via Metal Coordination".MACROMOLECULES 53.8(2020):2919-2931.