Applications of lignin-derived catalysts for green synthesis

doi:10.1016/j.gee.2019.01.003

	Applications of lignin-derived catalysts for green synthesis
	Zhu, Yuting 1,3; Li, Zhijing 2; Chen, Jinzhu 2,4
刊名	GREEN ENERGY & ENVIRONMENT
	2019-07-01
卷号	4 期号:3 页码:210-244
关键词	Catalyst Green chemistry Lignin Pretreatment Synthesis
ISSN号	2096-2797
DOI	10.1016/j.gee.2019.01.003
通讯作者	Chen, Jinzhu(chenjz@jnu.edu.cn)
英文摘要	This review intends to introduce the application of lignin-derived catalyst for green organic synthesis over latest two decades and aims to present a renewable alternative for conventional catalyst for future industry application. The structure of lignin is initially introduced in this review. Then, various pretreatment and activation technologies of lignin are systematically presented, which includes physical activation for the formation of well-developed porosity and chemical activation to introduce catalytic active sites. Finally, the catalytic performances of various lignin-derived catalysts are rationally assessed and compared with conventional catalysts, which involves lignin-derived solid acids for hydrolysis, hydration, dehydration (trans)esterification, multi-component reaction and condensation, lignin-derived solid base for Knoevenagel reaction, lignin-derived electro-catalysts for electro-oxidation, oxygen reduction reaction, and lignin-derived supported transition metal catalysts for hydrogenation, oxidation, coupling reaction, tandem reaction, condensation reaction, ring-opening reaction, Friedel-Crafts-type reaction, Fischer-Tropsch synthesis, click reaction, Glaser reaction, cycloaddition and (trans)esterification. The above lignin-derived catalysts thus successfully promote the transformations of organic compounds, carbon dioxide, biomass-based cellulose, saccharide and vegetable oil into valuable chemicals and fuels. At the end of this review, some perspectives are given on the current issues and tendency on the lignin-derived catalysts for green chemistry. (C) 2019, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V.
资助项目	National Natural Science Foundation of China[U1810111] ; Natural Science Foundation of Guangdong Province, China[2018B030311010] ; Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University[2018BCE002] ; Fundamental Research Funds for the Central Universities[21617431]
WOS关键词	HIERARCHICAL POROUS CARBONS ; SOLID ACID CATALYST ; ONE-POT SYNTHESIS ; ACTIVATED CARBON ; KRAFT LIGNIN ; LIGNOSULFONIC ACID ; IONIC LIQUID ; THERMOCHEMICAL CONVERSION ; CHEMICAL ACTIVATION ; MICROWAVE PYROLYSIS
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Energy & Fuels ; Engineering
语种	英语
出版者	KEAI PUBLISHING LTD
WOS记录号	WOS:000493350800003
资助机构	National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province, China ; Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University ; Fundamental Research Funds for the Central Universities
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/26069]
专题	中国科学院广州能源研究所
通讯作者	Chen, Jinzhu
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 2.Jinan Univ, Coll Chem & Mat Sci, Guangdong Engn & Technol Res Ctr Graphene Based M, Dept Chem, 601 Huangpu Ave West, Guangzhou 510632, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China 4.Zhejiang Univ, Dept Chem & Biol Engn, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 310027, Zhejiang, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Yuting,Li, Zhijing,Chen, Jinzhu. Applications of lignin-derived catalysts for green synthesis[J]. GREEN ENERGY & ENVIRONMENT,2019,4(3):210-244.
APA	Zhu, Yuting,Li, Zhijing,&Chen, Jinzhu.(2019).Applications of lignin-derived catalysts for green synthesis.GREEN ENERGY & ENVIRONMENT,4(3),210-244.
MLA	Zhu, Yuting,et al."Applications of lignin-derived catalysts for green synthesis".GREEN ENERGY & ENVIRONMENT 4.3(2019):210-244.