Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96% for Electrocatalytic CO2 Reduction to CO

doi:10.1002/anie.201912845

	Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96% for Electrocatalytic CO2 Reduction to CO
	Zhuang, Shengli 1,2; Chen, Dong 3; Liao, Lingwen 1,2; Zhao, Yan 1,2; Xia, Nan 1,2; Zhang, Wenhao 1,2; Wang, Chengming 4; Yang, Jun 3; Wu, Zhikun 1,2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2020-02-17
卷号	59
关键词	cadmium CO2 reduction electrocatalysis gold nanoclusters two-phase anti-galvanic reduction
ISSN号	1433-7851
DOI	10.1002/anie.201912845
通讯作者	Yang, Jun(jyang@ipe.ac.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
英文摘要	Metal nanoclusters have recently attracted considerable attention, not only because of their special size range but also because of their well-defined compositions and structures. However, subtly tailoring the compositions and structures of metal nanoclusters for potential applications remains challenging. Now, a two-phase anti-galvanic reduction (AGR) method is presented for precisely tailoring Au-44(TBBT)(28) to produce Au47Cd2(TBBT)(31) nanoclusters with a hard-sphere random close-packed structure, exhibiting Faradaic efficiencies of up to 96% at -0.57 V for the electrocatalytic reduction of CO2 to CO.
资助项目	National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21925303] ; National Natural Science Foundation of China[21905284] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21706265] ; National Natural Science Foundation of China[21603234] ; National Natural Science Foundation of China[21573212] ; National Natural Science Foundation of China[21573240] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; China Postdoctoral Science Foundation[Y94G4E356B] ; Key Program of 13th five-year plan, CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002] ; National Key R&D Program of China[2017YFA0207302] ; Center of Mesosicence, Institute of Process Engineering Chinese Academy of sciences[MPCS-2019-A-09] ; CASHIPS DirectorQs Fund[BJPY2019A02]
WOS关键词	ANTI-GALVANIC REDUCTION ; THIOLATE-PROTECTED GOLD ; AU-25 ; CLUSTERS ; ELECTROREDUCTION ; NANOPARTICLES ; ATOMS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000519891700002
资助机构	National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; Key Program of 13th five-year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Key R&D Program of China ; Center of Mesosicence, Institute of Process Engineering Chinese Academy of sciences ; CASHIPS DirectorQs Fund
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/103825]
专题	中国科学院合肥物质科学研究院
通讯作者	Yang, Jun; Wu, Zhikun
作者单位	1.Chinese Acad Sci, Key Lab Mat Phys, Anhui Key Lab Nanomat & Nanotechnol, CAS Ctr Excellence Nanosci,Inst Solid State Phys, Hefei 230031, Anhui, Peoples R China 2.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Zhuang, Shengli,Chen, Dong,Liao, Lingwen,et al. Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96% for Electrocatalytic CO2 Reduction to CO[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2020,59.
APA	Zhuang, Shengli.,Chen, Dong.,Liao, Lingwen.,Zhao, Yan.,Xia, Nan.,...&Wu, Zhikun.(2020).Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96% for Electrocatalytic CO2 Reduction to CO.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59.
MLA	Zhuang, Shengli,et al."Hard-Sphere Random Close-Packed Au47Cd2(TBBT)(31) Nanoclusters with a Faradaic Efficiency of Up to 96% for Electrocatalytic CO2 Reduction to CO".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59(2020).