k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge | |
Wu Hongping; Pan Shilie; Poeppelmeier Kenneth R.; Li Hongyi; Jia Dianzeng; Chen Zhaohui; Fan Xiaoyun; Yang Yun; Rondinelli James M.; Luo Haosu | |
刊名 | Journal of the American Chemical Society |
2011 | |
卷号 | 133期号:20页码:7786-7790 |
ISSN号 | 0002-7863 |
DOI | 10.1021/ja111083x |
英文摘要 | Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3. |
学科主题 | Chemistry |
WOS记录号 | WOS:000291580400034 |
公开日期 | 2012-11-29 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/1425] |
专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Pan Shilie |
作者单位 | 1.Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai 201800, Peoples R China 2.Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA 3.Northwestern Univ, Dept Chem, Evanston, IL 60208 USA 4.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China 5.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Wu Hongping,Pan Shilie,Poeppelmeier Kenneth R.,et al. k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge[J]. Journal of the American Chemical Society,2011,133(20):7786-7790. |
APA | Wu Hongping.,Pan Shilie.,Poeppelmeier Kenneth R..,Li Hongyi.,Jia Dianzeng.,...&Luo Haosu.(2011).k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge.Journal of the American Chemical Society,133(20),7786-7790. |
MLA | Wu Hongping,et al."k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge".Journal of the American Chemical Society 133.20(2011):7786-7790. |
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