Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters

doi:10.1002/cjoc.201300063

	Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters
	Zhu, Ting-Shun; Xu, Ming-Hua
刊名	CHINESE JOURNAL OF CHEMISTRY
	2013-03
卷号	31 期号:3 页码:321-328
关键词	asymmetric catalysis rhodium sulfur-olefin ligand 1 2-addition stereoselectivity reversal
ISSN号	1001-604X
DOI	10.1002/cjoc.201300063
文献子类	Article
英文摘要	Simple and readily available chiral N-(sulfinyl)allylamines have been developed as efficient novel ligands for the rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to challenging aliphatic -ketoesters. By employing the linear or branched sulfinamide-olefin ligands, interesting enantioselectivity as well as regioselectivity reversal in the related asymmetric additions were observed.
资助项目	National Natural Science Foundation of China[20972172] ; National Natural Science Foundation of China[21021063]
WOS关键词	ARYL BORONIC ACIDS ; ALPHA-KETOESTERS ; ALPHA,BETA-UNSATURATED KETONES ; ENANTIOSELECTIVE 1,2-ADDITION ; ADDITION-REACTIONS ; HYDROXYLATION ; ALDEHYDES ; PALLADACYCLES ; 1,2-DIKETONES ; 1,4-ADDITION
WOS研究方向	Chemistry
语种	英语
CSCD记录号	CSCD:4793359
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000316809600005
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/277706]
专题	药物化学研究室
通讯作者	Xu, Ming-Hua
作者单位	Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Ting-Shun,Xu, Ming-Hua. Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters[J]. CHINESE JOURNAL OF CHEMISTRY,2013,31(3):321-328.
APA	Zhu, Ting-Shun,&Xu, Ming-Hua.(2013).Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters.CHINESE JOURNAL OF CHEMISTRY,31(3),321-328.
MLA	Zhu, Ting-Shun,et al."Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters".CHINESE JOURNAL OF CHEMISTRY 31.3(2013):321-328.