Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates

doi:10.1055/s-0033-1338418

	Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates
	Wang, Hui; Xu, Ming-Hua
刊名	SYNTHESIS-STUTTGART
	2013-08
卷号	45 期号:15 页码:2125-2133
关键词	asymmetric catalysis cyclization arylation rhodium boron ligands sulfamidates heterocycles
ISSN号	0039-7881
DOI	10.1055/s-0033-1338418
文献子类	Article
英文摘要	A highly efficient asymmetric arylation of cyclic N-sulfonyl aldimines with arylboronic acids catalyzed by a rhodium/sulfur-olefin ligand complex under mild conditions is described. A wide range 4-aryl-3,4-dihydro-1,2,3-benzoxathiazine 2,2-dioxides were obtained in extremely high yields (93-99%) and high enantiomeric purities (97-99% ee).
资助项目	National Natural Science Foundation of China[20972172] ; National Natural Science Foundation of China[21021063]
WOS关键词	SULFUR-OLEFIN LIGANDS ; H BOND OXIDATION ; SULFAMATE ESTERS ; NUCLEOPHILIC DISPLACEMENTS ; INTRAMOLECULAR AMIDATION ; RUTHENIUM PORPHYRINS ; SULFONAMIDE MOIETIES ; CONJUGATE ADDITIONS ; AMINE DERIVATIVES ; ALPHA-KETOESTERS
WOS研究方向	Chemistry
语种	英语
出版者	GEORG THIEME VERLAG KG
WOS记录号	WOS:000322065900015
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/277525]
专题	药物化学研究室
通讯作者	Xu, Ming-Hua
作者单位	Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
推荐引用方式 GB/T 7714	Wang, Hui,Xu, Ming-Hua. Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates[J]. SYNTHESIS-STUTTGART,2013,45(15):2125-2133.
APA	Wang, Hui,&Xu, Ming-Hua.(2013).Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates.SYNTHESIS-STUTTGART,45(15),2125-2133.
MLA	Wang, Hui,et al."Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates".SYNTHESIS-STUTTGART 45.15(2013):2125-2133.