Rh(III)-Catalyzed C-H Amidation with N-Hydroxycarbamates: A New Entry to N-Carbamate-Protected Arylamines

doi:10.1021/ol403477w

	Rh(III)-Catalyzed C-H Amidation with N-Hydroxycarbamates: A New Entry to N-Carbamate-Protected Arylamines
	Zhou, Bing; Du, Juanjuan; Yang, Yaxi; Feng, Huijin; Li, Yuanchao
刊名	ORGANIC LETTERS
	2014-01-17
卷号	16 期号:2 页码:592-595
ISSN号	1523-7060
DOI	10.1021/ol403477w
文献子类	Article
英文摘要	An unprecedented Rh(III)-catalyzed direct intermolecular C-H amidation with N-hydroxycarbamates has been developed. Different directing groups, such as pyridine, pyrimidine, pyrazole, and N-OMe oxime, can be employed in this C-H amidation process, providing valuable N-carbamate-protected arylamines (e.g., Cbz, Moz, Ac, Boc, and Fmoc). More importantly, this process may afford a new avenue for intermolecular C-H amidation where readily available N-hydroxycarbamates can be used as the nitrogen source
资助项目	National Natural Science Foundation of China[21302200]
WOS关键词	CATALYZED DIRECT AMINATION ; BOND FORMATION ; ROOM-TEMPERATURE ; INTERNAL ALKYNES ; SULFONYL AZIDES ; MILD CONDITIONS ; DIRECT ADDITION ; DIAZO-COMPOUNDS ; BENZOIC-ACIDS ; ACTIVATION
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000330098400068
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/277226]
专题	药物化学研究室
通讯作者	Zhou, Bing
作者单位	Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Bing,Du, Juanjuan,Yang, Yaxi,et al. Rh(III)-Catalyzed C-H Amidation with N-Hydroxycarbamates: A New Entry to N-Carbamate-Protected Arylamines[J]. ORGANIC LETTERS,2014,16(2):592-595.
APA	Zhou, Bing,Du, Juanjuan,Yang, Yaxi,Feng, Huijin,&Li, Yuanchao.(2014).Rh(III)-Catalyzed C-H Amidation with N-Hydroxycarbamates: A New Entry to N-Carbamate-Protected Arylamines.ORGANIC LETTERS,16(2),592-595.
MLA	Zhou, Bing,et al."Rh(III)-Catalyzed C-H Amidation with N-Hydroxycarbamates: A New Entry to N-Carbamate-Protected Arylamines".ORGANIC LETTERS 16.2(2014):592-595.