Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes | |
Zhao Fei1; Jia Xiuwen1; Wang Dongping1; Fei Chaoli1; Wu Chenglin2,3; Wang Jiang2,3![]() ![]() | |
刊名 | CHINESE JOURNAL OF ORGANIC CHEMISTRY
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2017-02-25 | |
卷号 | 37期号:2页码:284-300 |
关键词 | metal-catalyzed carbon-hetero bonds alkynes addition reactions |
ISSN号 | 0253-2786 |
DOI | 10.6023/cjoc201607035 |
文献子类 | Review |
英文摘要 | The addition of carbon-hetero bonds to alkynes has become an important apporach for the functionalization of carbon-carbon triple bonds. It can construct two bonds, namely one carbon-carbon bond and one carbon-hetero bond, in a single one step. These addition reactions feature high efficiency and high atom-economy. In recent years, metal-catalyzed (Al, Fe, Ni, Cu, Ga, Ru, Rh, Pd, Hf, Ir, Pt, Au, Bi, etc.) addition of many various kinds of carbon-hetero bonds to alkynes has achieved lots of important developments. According to the types of carbon-hetero bonds, the addition of 8 different kinds of carbon-hetero bonds [C-H, C-B, C-N, C-O, C-Si, C-S, C-X (X=Cl, Br, I), C-Se] to alkynes is reviewed in this paper, and the reaction conditions, reaction selectivities (regioselectivities and stereoselectivities) and reaction mechanisms are also discussed and summarized. |
资助项目 | National Natural Science Foundation of China[21602022] ; National Natural Science Foundation of China[21372235] ; Open Project Program of Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province[ARRLKF15-01] |
WOS关键词 | C-N BOND ; INTRAMOLECULAR TRANS-VINYLSILYLATION ; TERMINAL ALKYNES ; UNACTIVATED ALKYNES ; ACID-CHLORIDES ; REGIOSELECTIVE CYANOTHIOLATION ; 2,3-DISUBSTITUTED BENZOFURANS ; CYCLOISOMERIZATION REACTION ; STEREOSELECTIVE-SYNTHESIS ; CONVENIENT SYNTHESIS |
WOS研究方向 | Chemistry |
语种 | 中文 |
CSCD记录号 | CSCD:5947933 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000397808100003 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.183/handle/2S10ELR8/272766] ![]() |
专题 | 药物化学研究室 |
通讯作者 | Liu Hong |
作者单位 | 1.Chengdu Univ, Sichuan Ind Inst Antibiot, Antibiot Res & Reevaluat Key Lab Sichuan Prov, Chengdu 610052, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Key Lab Receptor Res, Shanghai 201203, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao Fei,Jia Xiuwen,Wang Dongping,et al. Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2017,37(2):284-300. |
APA | Zhao Fei.,Jia Xiuwen.,Wang Dongping.,Fei Chaoli.,Wu Chenglin.,...&Liu Hong.(2017).Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes.CHINESE JOURNAL OF ORGANIC CHEMISTRY,37(2),284-300. |
MLA | Zhao Fei,et al."Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes".CHINESE JOURNAL OF ORGANIC CHEMISTRY 37.2(2017):284-300. |
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