The resolution of aglinin A epimers and their NMR assignments

doi:10.1080/10286020.2012.745854

CORC > 上海药物研究所 > 中国科学院上海药物研究所 > 天然药物化学研究室

	The resolution of aglinin A epimers and their NMR assignments
	Feng, Tian-Xiang 1,2; Qu, Shi-Jin2 ; Tan, Jun-Jie2 ; Jiang, Kun 2; Tan, Chang-Heng2 ; Lin, Shuang-Jun 1
刊名	JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH
	2013
卷号	15 期号:1 页码:89-93
关键词	aglinin A Aglaia Meliaceae -gauche effect
ISSN号	1028-6020
DOI	10.1080/10286020.2012.745854
文献子类	Article
英文摘要	Aglinin A (1) is a mixture of C24-epimeric 20S,24-epoxy-24,25-dihydroxy-3,4-secodammar-4(28)-en-3-oic acid and present in plants of the family Meliaceae. The two epimers of 1 were resolved through an acetonide reaction, and the absolute configurations of two derivatives were deduced by the analysis of their 13C NMR differences induced by -gauche or steric effect. Based on it, the 13C NMR assignment of 24R-1 and 24S-1 was also established.
资助项目	National Science & Technology Major Project "Key New Drug Creation and Manufacturing Program"[2011ZX09307-002-03] ; National Natural Science Foundation of China[81072545] ; National Natural Science Foundation of China[21202182]
WOS关键词	AGLAIA ; CONSTITUENTS
WOS研究方向	Plant Sciences ; Chemistry ; Pharmacology & Pharmacy
语种	英语
出版者	TAYLOR & FRANCIS LTD
WOS记录号	WOS:000314452400014
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/277810]
专题	天然药物化学研究室分析化学研究室
通讯作者	Tan, Chang-Heng
作者单位	1.Shanghai Jiao Tong Univ, State Key Lab Microbial Metab, Sch Life Sci & Biotechnol, Shanghai 200030, Peoples R China; 2.Chinese Acad Sci, Dept Nat Med Chem, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
推荐引用方式 GB/T 7714	Feng, Tian-Xiang,Qu, Shi-Jin,Tan, Jun-Jie,et al. The resolution of aglinin A epimers and their NMR assignments[J]. JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH,2013,15(1):89-93.
APA	Feng, Tian-Xiang,Qu, Shi-Jin,Tan, Jun-Jie,Jiang, Kun,Tan, Chang-Heng,&Lin, Shuang-Jun.(2013).The resolution of aglinin A epimers and their NMR assignments.JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH,15(1),89-93.
MLA	Feng, Tian-Xiang,et al."The resolution of aglinin A epimers and their NMR assignments".JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH 15.1(2013):89-93.