Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies

doi:10.1007/s10562-019-02813-8

	Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies
	Shi, Gansheng; Mahmood, Asad; Lu, Guanhong; Wang, Xiao; Tong, Shengrui; Ge, Maofa; Xie, Xiaofeng; Sun, Jing
刊名	CATALYSIS LETTERS
	2019-10-01
卷号	149 期号:10 页码:2728
关键词	Ethylene Acetaldehyde TiO2 (001) surface Saddle-like structure Carbonyl group Adsorption mechanism
ISSN号	1011-372X
DOI	10.1007/s10562-019-02813-8
文献子类	Article
英文摘要	In this work, the adsorption and photodegradation of acetaldehyde and ethylene on TiO2 nanoparticles (NPs) with dominant {001} facets were studied. Additionally, the first principle calculation was used to complement the experimental results. TiO2 NPs were synthesized by using a hydrothermal method. The experimental results indicated that adsorption amount of acetaldehyde on TiO2 {001} facets is higher than ethylene, with the initial concentration as 50010ppm. Photodegradation efficiency of 88% was achieved for acetaldehyde in contrast to 17% for ethylene at flow rate of 10sccm. The first principle calculations show that the adsorption energy (E-ads) for acetaldehyde is 0.603eV and that of ethylene is 0.251eV. This study is imperative for understanding the adsorption and photodegradation process of acetaldehyde and ethylene, two typical VOCs, and helpful to design the photocatalysts with high efficiency. [GRAPHICS] .
WOS研究方向	Chemistry
语种	英语
出版者	SPRINGER
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/26800]
专题	中国科学院上海硅酸盐研究所
推荐引用方式 GB/T 7714	Shi, Gansheng,Mahmood, Asad,Lu, Guanhong,et al. Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies[J]. CATALYSIS LETTERS,2019,149(10):2728.
APA	Shi, Gansheng.,Mahmood, Asad.,Lu, Guanhong.,Wang, Xiao.,Tong, Shengrui.,...&Sun, Jing.(2019).Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies.CATALYSIS LETTERS,149(10),2728.
MLA	Shi, Gansheng,et al."Adsorption and Photodegradation of Acetaldehyde and Ethylene on TiO2 (001) Surface: Experimental and First Principle Studies".CATALYSIS LETTERS 149.10(2019):2728.