Double-shelled hollow carbon spheres confining tin as high- performance electrodes for lithium ion batteries | |
Sun, Li; Ma, Tiantian; Zhang, Jun; Guo, Xiangxin; Yan, Chenglin; Liu, Xianghong | |
刊名 | ELECTROCHIMICA ACTA |
2019-10-20 | |
卷号 | 321 |
关键词 | Negative electrode Hollow structure Long cycling Structure design Tin |
ISSN号 | 0013-4686 |
DOI | 10.1016/j.electacta.2019.134672 |
文献子类 | Article |
英文摘要 | Alloy-type materials hold a great potential as the negative electrodes for next generation lithium-ion batteries with high energy and low cost. However, the huge volume expansion of alloy-type materials caused by lithium alloying inevitably leads to poor cycle stability. Herein, we propose a rational design of a sandwich structure of carbon/Sn/carbon hollow spheres by a template-engaged method. The structure effect of the novel carbon/Sn/carbon spheres on the lithium storage performances is elucidated by various means of characterization and electrochemical tests. A stable and high reversible capacity of 1100 mA h g(-1) is retained after 130 cycles at 0.1 A g(-1), significantly higher than that (187 mA h g(-1) ) of Sn/carbon hollow spheres. Furthermore, a superior rate capability is obtained for carbon/Sn/carbon spheres, e.g., showing a high capacity of 430 mA h g(-1) at 5 A g(-1). The excellent electrochemical properties of carbon/Sn/carbon against Sn/carbon are ascribed to a unique nano-confinement from the double-shelled carbons with very good structure stability and contribution of pseudocapacitive storage of lithium. These results indicate that the sandwich structure of carbon/Sn/carbon is highly effective to design electrode materials with enhanced performances. (C) 2019 Published by Elsevier Ltd. |
WOS研究方向 | Electrochemistry |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/26771] |
专题 | 中国科学院上海硅酸盐研究所 |
推荐引用方式 GB/T 7714 | Sun, Li,Ma, Tiantian,Zhang, Jun,et al. Double-shelled hollow carbon spheres confining tin as high- performance electrodes for lithium ion batteries[J]. ELECTROCHIMICA ACTA,2019,321. |
APA | Sun, Li,Ma, Tiantian,Zhang, Jun,Guo, Xiangxin,Yan, Chenglin,&Liu, Xianghong.(2019).Double-shelled hollow carbon spheres confining tin as high- performance electrodes for lithium ion batteries.ELECTROCHIMICA ACTA,321. |
MLA | Sun, Li,et al."Double-shelled hollow carbon spheres confining tin as high- performance electrodes for lithium ion batteries".ELECTROCHIMICA ACTA 321(2019). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论