Highly enantioselective reduction of ketones by chiral diol-modified lithium aluminum hydride reagents | |
Sun KP(孙鲲鹏)![]() | |
刊名 | Tetrahedron Letters
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2006 | |
卷号 | 47期号:4页码:463-465 |
关键词 | asymmetric reduction ketone diol lithium tetrahydridoaluminate |
ISSN号 | 0040-4039 |
通讯作者 | 徐贤伦 |
中文摘要 | Some readily available chiral diols from indene and (D)-mannitol were investigated as chiral modifiers in lithium aluminum hydride reduction of ketones, and it was discovered that further modification of these reducing reagents by a simple a-amino alcohol resulted in a remarkable increase in optical yield. Among the investigated chiral modifiers, chiral diol I gave the highest enantio selectivities. |
学科主题 | 物理化学 |
收录类别 | SCI |
资助信息 | National Nature Science Foundation of China (No. 29933050) |
语种 | 英语 |
WOS记录号 | WOS:000234624600013 |
公开日期 | 2013-08-27 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/3684] ![]() |
专题 | 兰州化学物理研究所_绿色化学研究发展中心 |
推荐引用方式 GB/T 7714 | Sun KP. Highly enantioselective reduction of ketones by chiral diol-modified lithium aluminum hydride reagents[J]. Tetrahedron Letters,2006,47(4):463-465. |
APA | 孙鲲鹏.(2006).Highly enantioselective reduction of ketones by chiral diol-modified lithium aluminum hydride reagents.Tetrahedron Letters,47(4),463-465. |
MLA | 孙鲲鹏."Highly enantioselective reduction of ketones by chiral diol-modified lithium aluminum hydride reagents".Tetrahedron Letters 47.4(2006):463-465. |
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