Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids

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	Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids
	Zhang QH(张庆华); He YD(何昱德); Li DM(李冬梅); Shi F(石峰); Deng YQ(邓友全); Deng YQ(邓友全)
刊名	Journal of Molecular Catalysis A: Chemical
	2006
卷号	244 页码:64-67
关键词	Nitrobenzene Carbon monoxide Carbonylation Ionic liquids Palladium complex
ISSN号	1381-1169
通讯作者	邓友全
中文摘要	Based on the diversity of ionic liquids, i.e. tunable structure and physicochemical properties, a series of functional ionic liquids and palladium complexes were investigated, and a highly effective catalyst system, Pd(phen)Cl2-BAcImPF6 ionic liquid (phen = 1,10-phenanthroline; BAcIm = 1-butyl-3-acetic acid-imidazolium), was developed for the reductive carbonylation of nitrobenzene to give the corresponding carbamate with higher than 90% of conversion and selectivity at 150 ◦C and 6MPa carbon monoxide. The high catalytic performance is attributed to the acidic function of the BAcImPF6 ionic liquid and the interaction between Pd(phen)Cl2 and the ionic liquid to form the catalytically active palladium complex Pd(phen)2(PF6)2.
学科主题	物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation of China (No: 20225309)
语种	英语
WOS记录号	WOS:000235263100010
公开日期	2013-08-27
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3670]
专题	兰州化学物理研究所_绿色化学研究发展中心
通讯作者	Deng YQ(邓友全); Deng YQ(邓友全)
推荐引用方式 GB/T 7714	Zhang QH,He YD,Li DM,et al. Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids[J]. Journal of Molecular Catalysis A: Chemical,2006,244:64-67.
APA	张庆华,何昱德,李冬梅,石峰,邓友全,&邓友全.(2006).Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids.Journal of Molecular Catalysis A: Chemical,244,64-67.
MLA	张庆华,et al."Developing effective catalyst system for reductive carbonylation of nitrobenzene based on the diversity of ionic liquids".Journal of Molecular Catalysis A: Chemical 244(2006):64-67.