Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride

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	Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride
	Deng YQ(邓友全); Deng YQ(邓友全)
刊名	Journal of Molecular Catalysis A: Chemical
	2006
卷号	246 页码:70-75
关键词	[BMIm]BF4 Esterification Tertiary alcohol Acetic anhydride
ISSN号	1381-1169
通讯作者	邓友全
中文摘要	Esterification of tert-butanol by acetic anhydride, a typical acid–base catalytic reaction, was conducted with excellent selectivity and high yield in a neutral ionic liquid [BMIm]BF4 (1-butyl-3-methylimidazolium tetrafluoroborate). Many other tertiary alcohols could also be successfully converted to the corresponding esters in [BMIm]BF4. Separation of product and recovery and reuse of ionic liquid are all convenient in this system. Here, the need for catalysts is avoided through the use of catalytically active ionic liquids as solvents.
学科主题	物理化学
收录类别	SCI
资助信息	National Natural Science Foundation of China (No. 20225309;20533080)
语种	英语
WOS记录号	WOS:000236061800012
公开日期	2013-08-27
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3666]
专题	兰州化学物理研究所_绿色化学研究发展中心
通讯作者	Deng YQ(邓友全); Deng YQ(邓友全)
推荐引用方式 GB/T 7714	Deng YQ,Deng YQ. Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride[J]. Journal of Molecular Catalysis A: Chemical,2006,246:70-75.
APA	邓友全,&邓友全.(2006).Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride.Journal of Molecular Catalysis A: Chemical,246,70-75.
MLA	邓友全,et al."Neutral ionic liquid [BMIm]BF4 promoted highly selective esterification of tertiary alcohols by acetic anhydride".Journal of Molecular Catalysis A: Chemical 246(2006):70-75.