Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids | |
Deng YQ(邓友全); Deng YQ(邓友全); Zhang QH(张庆华); Shi F(石峰) | |
刊名 | Journal of Molecular Catalysis A: Chemical |
2007 | |
卷号 | 271页码:89-92 |
关键词 | Green chemistry Ionic liquid Carbamates Amine Non-phosgene |
ISSN号 | 1381-1169 |
通讯作者 | 邓友全 |
中文摘要 | Selective synthesis of carbamates from amines and dimethyl carbonate were studied in the presence of various ionic liquids as catalysts. The –SO3H-functionalized ionic liquid was found to be the most active catalyst among the applied ionic liquids, and nearly 100% conversion and 95% selectivity were achieved when using 1,6-hexanediamine as reactant. The acid functional ionic liquid catalyst system is also readily separable and reusable after reaction. |
学科主题 | 物理化学 |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China (Nos. 20225309;20533080) |
语种 | 英语 |
WOS记录号 | WOS:000246908500016 |
公开日期 | 2013-08-20 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/3652] |
专题 | 兰州化学物理研究所_绿色化学研究发展中心 |
通讯作者 | Deng YQ(邓友全); Deng YQ(邓友全) |
推荐引用方式 GB/T 7714 | Deng YQ,Deng YQ,Zhang QH,et al. Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids[J]. Journal of Molecular Catalysis A: Chemical,2007,271:89-92. |
APA | 邓友全,邓友全,张庆华,&石峰.(2007).Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids.Journal of Molecular Catalysis A: Chemical,271,89-92. |
MLA | 邓友全,et al."Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids".Journal of Molecular Catalysis A: Chemical 271(2007):89-92. |
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