Chiral interfacial assembly of a trigonal schiff base compound with TPPS in organized molecular films

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > 固体润滑国家重点实验室

	Chiral interfacial assembly of a trigonal schiff base compound with TPPS in organized molecular films
	Jiao TF(焦体峰); Zhou JX(周靖欣)
刊名	Applied Mechanics and Materials
	2012
卷号	236-237 页码:810-814
关键词	Trigonal Schiff base Chiral assembly TPPS Langmuir-Blodgett film Supramolecular assembly Spectral measurement
ISSN号	1722-6899
中文摘要	In order to investigate the chiral interfacial assembly of special amphiphile, a trigonal Schiff base compound with long alkyl chains was designed and synthesized, and its supramolecular assembly and interaction properties were investigated by spectral and morphological measurements. Condensed monolayers were obtained on pure water surface, in which flat and uniform domains were obtained for the monolayers. When an anionic tetrakis(4-sulfonatonphenyl)porphine (TPPS) was added into an acidic subphase, an in situ complex formation between the trigonal amphiphile and TPPS occurred. The complex monolayers were transferred onto solid substrate and TPPS existed as J-aggregate and J-aggregate in the complex films. Due to the multisited positive charges in the spacer on acidic subphase, the complex films of trigonal amphiphile with TPPS appeared as short nanorod structures and formed two-dimensional (2D) conglomerate chiral domains.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation of China (Grant No. 20903078);the China Postdoctoral Science Foundation (Grant No. 2011M500540);the Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No. CPRC020);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant No. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002);the Doctoral Foundation of Yanshan University (Grant No. B360)
语种	英语
公开日期	2013-07-12
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3281]
专题	兰州化学物理研究所_固体润滑国家重点实验室
推荐引用方式 GB/T 7714	Jiao TF,Zhou JX. Chiral interfacial assembly of a trigonal schiff base compound with TPPS in organized molecular films[J]. Applied Mechanics and Materials,2012,236-237:810-814.
APA	Jiao TF,&Zhou JX.(2012).Chiral interfacial assembly of a trigonal schiff base compound with TPPS in organized molecular films.Applied Mechanics and Materials,236-237,810-814.
MLA	Jiao TF,et al."Chiral interfacial assembly of a trigonal schiff base compound with TPPS in organized molecular films".Applied Mechanics and Materials 236-237(2012):810-814.