Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)

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	Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)
	Yuan W(袁渭) ; Dong X(董翔) ; Shi M(施敏) ; Patrick McDowell ; Li GG(李桂根)
刊名	Org. Lett.
	2012
卷号	14 期号:21 页码:5582-5585
ISSN号	1523-7060
其他题名	Rh(I)催化的亚乙烯基环丙烷-烯烃的P-K反应
通讯作者	施敏 ; 李桂根
英文摘要	An intramolecular Pauson-Khand type cycloaddition reaction of ene-vinylidenecyclopropanes with carbon monoxide has been established by using [Rh(COD)Cl](2) as the catalyst. The reaction was found to be highly efficient in solvents of 1,2-dichloroethane and 1,1,2,2-tetrachloroethane to give excellent yields of 90-99%. The reaction provides easy access to a series of fused 6,5-ring structures containing spiro-cyclopropane units that are useful for drug design and development. A mechanism of this cycloaddition process has been proposed accounting for structures of resulting products that were unambiguously assigned by X-ray diffractional analysis.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol302705z
语种	英语
WOS记录号	WOS:000311245600051
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/28177]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Yuan W,Dong X,Shi M,et al. Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)[J]. Org. Lett.,2012,14(21):5582-5585.
APA	袁渭,董翔,施敏,Patrick McDowell,&李桂根.(2012).Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO).Org. Lett.,14(21),5582-5585.
MLA	袁渭,et al."Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)".Org. Lett. 14.21(2012):5582-5585.