Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand

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	Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand
	Gu X(顾昕) ; Xu ZJ(徐镇江) ; Lu JY(卢嘉茵) ; Zhi ZM(支志明)
刊名	Synthesis
	2012
卷号	44 期号:21 页码:3307-3314
ISSN号	0039-7881
其他题名	联吡咯衍生膦络合物三氟甲磺酸银催化的亚胺叶立德不对称3加2环加成反应
通讯作者	徐镇江 ; 支志明
英文摘要	Two novel chiral bipyrrolidine-derived phosphine ligands L1 and L2 were synthesized. The 'AgOTf+L1' protocol catalyzes the asymmetric [3+2] cycloaddition of azomethine ylides with alkenes to give highly substituted pyrrolidines in good yields (up to 90%) with moderate to high diastereoselectivities (up to > 19:1 dr) and enantioselectivities (up to 76%).
学科主题	金属有机化学 ; 氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1055/s-0032-1316779
语种	英语
WOS记录号	WOS:000310461400011
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/28167]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Gu X,Xu ZJ,Lu JY,et al. Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand[J]. Synthesis,2012,44(21):3307-3314.
APA	顾昕,徐镇江,卢嘉茵,&支志明.(2012).Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand.Synthesis,44(21),3307-3314.
MLA	顾昕,et al."Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand".Synthesis 44.21(2012):3307-3314.