Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand | |
Gu X(顾昕) ; Xu ZJ(徐镇江) ; Lu JY(卢嘉茵) ; Zhi ZM(支志明) | |
刊名 | Synthesis
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2012 | |
卷号 | 44期号:21页码:3307-3314 |
ISSN号 | 0039-7881 |
其他题名 | 联吡咯衍生膦络合物三氟甲磺酸银催化的亚胺叶立德不对称3加2环加成反应 |
通讯作者 | 徐镇江 ; 支志明 |
英文摘要 | Two novel chiral bipyrrolidine-derived phosphine ligands L1 and L2 were synthesized. The 'AgOTf+L1' protocol catalyzes the asymmetric [3+2] cycloaddition of azomethine ylides with alkenes to give highly substituted pyrrolidines in good yields (up to 90%) with moderate to high diastereoselectivities (up to > 19:1 dr) and enantioselectivities (up to 76%). |
学科主题 | 金属有机化学 ; 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1055/s-0032-1316779 |
语种 | 英语 |
WOS记录号 | WOS:000310461400011 |
公开日期 | 2013-08-22 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/28167] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Gu X,Xu ZJ,Lu JY,et al. Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand[J]. Synthesis,2012,44(21):3307-3314. |
APA | 顾昕,徐镇江,卢嘉茵,&支志明.(2012).Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand.Synthesis,44(21),3307-3314. |
MLA | 顾昕,et al."Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand".Synthesis 44.21(2012):3307-3314. |
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