Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(III) complex of a D-4-symmetric Halterman porphyrin ligand

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	Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(III) complex of a D-4-symmetric Halterman porphyrin ligand
	Wang JC(王景翠) ; Xu ZJ(徐镇江) ; Guo Z(郭征) ; Deng QH(邓清海) ; Zhou CY(周聪颖) ; Wan XL(万小龙) ; Zhi ZM(支志明)
刊名	Chem. Commun.
	2012
卷号	48 期号:36 页码:4299-4301
ISSN号	1359-7345
其他题名	手性铱卟啉催化的分子间不对称碳氢、硅氢键插入反应
通讯作者	支志明
英文摘要	The chiral iridium porphyrin [Ir((-)-D-4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee).
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c2cc30441d
语种	英语
WOS记录号	WOS:000302363400007
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/28055]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Wang JC,Xu ZJ,Guo Z,et al. Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(III) complex of a D-4-symmetric Halterman porphyrin ligand[J]. Chem. Commun.,2012,48(36):4299-4301.
APA	王景翠.,徐镇江.,郭征.,邓清海.,周聪颖.,...&支志明.(2012).Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(III) complex of a D-4-symmetric Halterman porphyrin ligand.Chem. Commun.,48(36),4299-4301.
MLA	王景翠,et al."Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(III) complex of a D-4-symmetric Halterman porphyrin ligand".Chem. Commun. 48.36(2012):4299-4301.