Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

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	Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature
	Mu X(慕欣) ; Wu T(吴涛) ; Wang HY(王昊阳) ; Guo YL(郭寅龙) ; Liu GS(刘国胜)
刊名	J. Am. Chem. Soc.
	2012
卷号	134 期号:2 页码:878-881
ISSN号	0002-7863
其他题名	室温下钯催化活性烯烃的氧化芳基烷基化反应
通讯作者	刘国胜
英文摘要	A palladium-catalyzed intramolecular oxidative aryltrifluoromethylation reaction of activated alkenes has been explored. The reaction allows for an efficient synthesis of a variety of CF3-containing oxindoles. Preliminary mechanistic study indicated that the reaction involves a C-sp(3)-Pd-IV(CF3) intermediate, which undergoes reductive elimination to afford a C-sp(3)-CF3 bond.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ja210614y
语种	英语
WOS记录号	WOS:000301084300035
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/28033]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Mu X,Wu T,Wang HY,et al. Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature[J]. J. Am. Chem. Soc.,2012,134(2):878-881.
APA	慕欣,吴涛,王昊阳,郭寅龙,&刘国胜.(2012).Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature.J. Am. Chem. Soc.,134(2),878-881.
MLA	慕欣,et al."Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature".J. Am. Chem. Soc. 134.2(2012):878-881.