Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes

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	Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes
	Fu XP(付晓平) ; Yu SS(俞莎莎) ; Fan GQ(范国钦) ; Liu YH(刘元红) ; Li YX(李玉学)
刊名	Organometallics
	2012
卷号	31 期号:2 页码:531-534
ISSN号	0276-7333
其他题名	利用茂锆促进的1,3-丁二炔与醛的偶联反应高效合成顺式[3]联烯二醇
通讯作者	刘元红 ; 李玉学
英文摘要	A highly efficient and convenient method for the monozirconation of silyl- or tert-butyl-substituted 1,3-butadiynes using the Negishi reagent has been developed. The resulting zirconium butadiyne complexes undergo two syn-S(E)2' reactions with various aldehydes to yield the cis-[3]cumulenic diols with moderate to high diastereoselectivities. The silyl substituents at the butadiyne terminus show remarkable influence on the diastereoselectivity.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om201125z
语种	英语
WOS记录号	WOS:000299351500005
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/28031]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Fu XP,Yu SS,Fan GQ,et al. Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes[J]. Organometallics,2012,31(2):531-534.
APA	付晓平,俞莎莎,范国钦,刘元红,&李玉学.(2012).Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes.Organometallics,31(2),531-534.
MLA	付晓平,et al."Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes".Organometallics 31.2(2012):531-534.