Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds

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	Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds
	Lu BL(卢贝丽) ; Wei Y(魏音) ; Shi M(施敏)
刊名	Organometallics
	2012
卷号	31 期号:12 页码:4601-4609
ISSN号	0276-7333
其他题名	Rh(I)催化的亚乙烯基环丙烷和CO的[3+2+1]P-K类型环化反应: 一个高区域和高立体选择性合成氮或氧杂双环化合物的新方法
通讯作者	施敏
英文摘要	In this paper, a novel Rh(I)-catalyzed Pauson-Khand-type [3 + 2 + 1] cycloaddition reaction of ene-vinylidenecyclopropanes (Ene-VDCPs) and carbon monoxide (CO) has been developed to furnish a series of aza- and oxa-bicyclic compounds in moderate to good yields in a highly regio- and diastereoselective manner, which provides an alternative and efficient synthetic approach for the access of bicyclic cyclohexanone frameworks. The substrate scope and limitations and a plausible mechanism are discussed.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om3004288
语种	英语
WOS记录号	WOS:000305588000028
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/27961]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Lu BL,Wei Y,Shi M. Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds[J]. Organometallics,2012,31(12):4601-4609.
APA	卢贝丽,魏音,&施敏.(2012).Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds.Organometallics,31(12),4601-4609.
MLA	卢贝丽,et al."Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds".Organometallics 31.12(2012):4601-4609.