Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds | |
Lu BL(卢贝丽) ; Wei Y(魏音) ; Shi M(施敏) | |
刊名 | Organometallics
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2012 | |
卷号 | 31期号:12页码:4601-4609 |
ISSN号 | 0276-7333 |
其他题名 | Rh(I)催化的亚乙烯基环丙烷和CO的[3+2+1]P-K类型环化反应: 一个高区域和高立体选择性合成氮或氧杂双环化合物的新方法 |
通讯作者 | 施敏 |
英文摘要 | In this paper, a novel Rh(I)-catalyzed Pauson-Khand-type [3 + 2 + 1] cycloaddition reaction of ene-vinylidenecyclopropanes (Ene-VDCPs) and carbon monoxide (CO) has been developed to furnish a series of aza- and oxa-bicyclic compounds in moderate to good yields in a highly regio- and diastereoselective manner, which provides an alternative and efficient synthetic approach for the access of bicyclic cyclohexanone frameworks. The substrate scope and limitations and a plausible mechanism are discussed. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/om3004288 |
语种 | 英语 |
WOS记录号 | WOS:000305588000028 |
公开日期 | 2013-08-22 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/27961] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Lu BL,Wei Y,Shi M. Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds[J]. Organometallics,2012,31(12):4601-4609. |
APA | 卢贝丽,魏音,&施敏.(2012).Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds.Organometallics,31(12),4601-4609. |
MLA | 卢贝丽,et al."Rhodium(I)-Catalyzed Pauson-Khand-type [3+2+1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds".Organometallics 31.12(2012):4601-4609. |
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