Bronsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation

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	Bronsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation
	Wu L(吴亮) ; Qiu SF(邱水发) ; Liu GS(刘国生)
刊名	Org. Lett.
	2009
卷号	11 期号:12 页码:2707-2710
ISSN号	1523-7060
其他题名	Bronsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation
通讯作者	刘国生
英文摘要	A novel palladium-catalyzed intramolecular aerobic oxidative allylic C-H amination of olefins has been developed. Bronsted base can modulate the regioselectivity, favoring the formation of 7-membered rings. Mechanistic studies using deuterium-labeled substrates as probes support a rate-determining allylic C-H activation/irreversible reductive elimination pathway.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol900941t
语种	英语
WOS记录号	WOS:000266930900058
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/27871]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Wu L,Qiu SF,Liu GS. Bronsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation[J]. Org. Lett.,2009,11(12):2707-2710.
APA	吴亮,邱水发,&刘国生.(2009).Bronsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.Org. Lett.,11(12),2707-2710.
MLA	吴亮,et al."Bronsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation".Org. Lett. 11.12(2009):2707-2710.