Total Synthesis of Akuammiline Alkaloid (-)-Vincorine via Intramolecular Oxidative Coupling
Zi WW(资伟伟) ; Xie WQ(谢卫青) ; Ma DW(马大为)
刊名J. Am. Chem. Soc.
2012
卷号134期号:22页码:9126-9129
ISSN号0002-7863
其他题名经由分子内氧化偶联对Akuammiline生物碱(-)-Vincorine的全合成
通讯作者马大为
英文摘要An asymmetric total synthesis of the Akuammiline alkaloid (-)-vincorine (18 steps from 5-methoxytryptamine, 5% overall yield) is described. The key steps include Pd-catalyzed direct C-H functionalization of indole derivatives, organocatalyzed asymmetric Michael addition of aldehydes to alkylidene malonates, and intramolecular oxidative coupling between indole and malonate moieties.
学科主题生命有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1021/ja303602f
语种英语
WOS记录号WOS:000304837800027
公开日期2013-08-23
内容类型期刊论文
源URL[http://202.127.28.38/handle/331003/28503]  
专题上海有机化学研究所_生命有机化学国家重点实验室
推荐引用方式
GB/T 7714
Zi WW,Xie WQ,Ma DW. Total Synthesis of Akuammiline Alkaloid (-)-Vincorine via Intramolecular Oxidative Coupling[J]. J. Am. Chem. Soc.,2012,134(22):9126-9129.
APA 资伟伟,谢卫青,&马大为.(2012).Total Synthesis of Akuammiline Alkaloid (-)-Vincorine via Intramolecular Oxidative Coupling.J. Am. Chem. Soc.,134(22),9126-9129.
MLA 资伟伟,et al."Total Synthesis of Akuammiline Alkaloid (-)-Vincorine via Intramolecular Oxidative Coupling".J. Am. Chem. Soc. 134.22(2012):9126-9129.
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