Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents | |
Huang WZ(黄维洲) ; Ni CF(倪传法) ; Zhao YC(赵延川) ; Zhang W(张伟) ; DILMAN ALEXANDER D ; Hu JB(胡金波) | |
刊名 | Tetrahedron
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2012 | |
卷号 | 68期号:26页码:5137-5144 |
ISSN号 | 0040-4020 |
其他题名 | 利用二氟甲基硅烷试剂对杂环化合物中的C=N键进行亲核二氟甲基化反应 |
通讯作者 | 胡金波 |
英文摘要 | An efficient and straightforward nucleophilic difluoromethylation of C=N bonds in heterocycles under the activation of alkylating agents has been developed. Cyclic iminium salts derived from dihydroisoquinolines, quinolines, and pyridines were successfully difluoromethylated with sulfur-based fluoroalkyl silanes affording a series of new difluoromethylated nitrogen-containing heterocyclic compounds. (C) 2012 Elsevier Ltd. All rights reserved. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tet.2012.04.039 |
语种 | 英语 |
WOS记录号 | WOS:000305381700003 |
公开日期 | 2013-08-23 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/28231] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | Huang WZ,Ni CF,Zhao YC,et al. Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents[J]. Tetrahedron,2012,68(26):5137-5144. |
APA | 黄维洲,倪传法,赵延川,张伟,DILMAN ALEXANDER D,&胡金波.(2012).Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents.Tetrahedron,68(26),5137-5144. |
MLA | 黄维洲,et al."Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents".Tetrahedron 68.26(2012):5137-5144. |
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