Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids from chiral imines of trifluoropyruvate | |
Min QQ(闵巧桥) ; He CY(贺春阳) ; Zhou HB(周海滨) ; Zhang XG(张新刚) | |
刊名 | Chem. Commun.
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2010 | |
卷号 | 46期号:42页码:8029-8031 |
ISSN号 | 1359-7345 |
其他题名 | 基于手性三氟丙酮酸酯亚胺高立体选择性合成alpha-三氟甲基-alpha-氨基酸 |
通讯作者 | 张新刚 |
英文摘要 | An efficient method for highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids was developed via indium mediated allylation of (R)-phenylglycinol methyl ether based imines of trifluoropyruvate in good yields with high diastereoselectivities at room temperature; to illustrate the application of this method in organic synthesis, 2-allyl-2-(trifluoromethyl) aziridine was prepared in an efficient manner. |
学科主题 | 氟化学 ; 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/c0cc02408b |
语种 | 英语 |
WOS记录号 | WOS:000283260400049 |
公开日期 | 2013-08-23 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/28203] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | Min QQ,He CY,Zhou HB,et al. Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids from chiral imines of trifluoropyruvate[J]. Chem. Commun.,2010,46(42):8029-8031. |
APA | 闵巧桥,贺春阳,周海滨,&张新刚.(2010).Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids from chiral imines of trifluoropyruvate.Chem. Commun.,46(42),8029-8031. |
MLA | 闵巧桥,et al."Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids from chiral imines of trifluoropyruvate".Chem. Commun. 46.42(2010):8029-8031. |
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