Metal-Free Intramolecular Aziridination of Allylic Carbamates Mediated by Hypervalent Iodine Compounds

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	Metal-Free Intramolecular Aziridination of Allylic Carbamates Mediated by Hypervalent Iodine Compounds
	Deng QH(邓清海) ; Wang JC(王景翠) ; Xu ZJ(徐镇江) ; Zhou CY(周聪颖) ; Zhi ZM(支志明)
刊名	Synthesis
	2011
期号	18 页码:2959-2967
ISSN号	0039-7881
其他题名	高碘化合物介导的烯丙醇胺基甲酸酯的分子内氮杂环丙烷化反应
通讯作者	徐镇江 ; 支志明
英文摘要	An efficient and practical hypervalent iodine compound mediated metal-free intramolecular aziridination reaction of allylic carbamates was developed. Analytically pure aziridines were obtained in high yields by simple filtration of the reaction mixture. In situ ring opening of the aziridines provides an easy access to useful vicinal amino alcohol derivatives and diamine compounds. Up to 16% ee was obtained when chiral hypervalent iodine compound was used.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1055/s-0030-1260150
语种	英语
WOS记录号	WOS:000295686400012
公开日期	2013-08-21
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/27825]
专题	上海有机化学研究所_上海有机化学研究所
推荐引用方式 GB/T 7714	Deng QH,Wang JC,Xu ZJ,et al. Metal-Free Intramolecular Aziridination of Allylic Carbamates Mediated by Hypervalent Iodine Compounds[J]. Synthesis,2011(18):2959-2967.
APA	邓清海,王景翠,徐镇江,周聪颖,&支志明.(2011).Metal-Free Intramolecular Aziridination of Allylic Carbamates Mediated by Hypervalent Iodine Compounds.Synthesis(18),2959-2967.
MLA	邓清海,et al."Metal-Free Intramolecular Aziridination of Allylic Carbamates Mediated by Hypervalent Iodine Compounds".Synthesis .18(2011):2959-2967.