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	Temperature-dependent Raman spectroscopic study of ferroelastic K2Sr(MoO4)
	Zhang, Ji1; Zhang, De-Ming3; Zhang, Ran-Ran2
刊名	CHINESE PHYSICS B
	2018-11-01
卷号	27期号:11页码:5
关键词	ferroelastics K2Sr(MoO4)(2) crystal Raman spectroscopy phase transition
ISSN号	1674-1056
DOI	10.1088/1674-1056/27/11/117801
通讯作者	Zhang, Ji(18956063545@189.cn)
英文摘要	Raman scattering measurements of K2Sr(MoO4)(2) were performed in the temperature range of 25-750 degrees C. The Raman spectrum of the low-temperature phase alpha-K2Sr(MoO4)(2) that was obtained by first-principle calculations indicated that the Raman bands in the wavenumber region of 250-500 cm(-1) are related to Mo-O bending vibrations in MoO4 tetrahedra, while the Raman bands in the wavenumber region of 650-950 cm(-1)are attributed to stretching vibrations of Mo-O bonds. The temperature-dependent Raman spectra reveal that K2Sr(MoO4)(2) exhibits two sets of modifications in the Raman spectra at similar to 150 degrees C and similar to 475 degrees C, attributed to structural phase transitions. The large change of the Raman spectra in the temperature range of 150 degrees C to 475 degrees C suggests structural instability of the medium-temperature phase beta-K2Sr(MoO4)(2).
资助项目	Natural Science Foundation of Anhui Province, China[KJ2018A0588] ; Natural Science Foundation of Anhui Province, China[KJ2017A625]
WOS关键词	GENERALIZED GRADIENT APPROXIMATION ; INFRARED-SPECTRA ; TRANSITIONS ; MOLYBDATES ; PHOSPHATE ; CAMOO4 ; CAWO4
WOS研究方向	Physics
语种	英语
出版者	IOP PUBLISHING LTD
WOS记录号	WOS:000450996100001
资助机构	Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China ; Natural Science Foundation of Anhui Province, China
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/40158]
专题	合肥物质科学研究院_中科院安徽光学精密机械研究所 合肥物质科学研究院_中科院强磁场科学中心
通讯作者	Zhang, Ji
作者单位	1.An Hui Xin Hua Univ, Hefei 230088, Anhui, Peoples R China 2.Chinese Acad Sci, High Magnet Field Lab, Hefei 230031, Anhui, Peoples R China 3.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Ji,Zhang, De-Ming,Zhang, Ran-Ran. Temperature-dependent Raman spectroscopic study of ferroelastic K2Sr(MoO4)[J]. CHINESE PHYSICS B,2018,27(11):5.
APA	Zhang, Ji,Zhang, De-Ming,&Zhang, Ran-Ran.(2018).Temperature-dependent Raman spectroscopic study of ferroelastic K2Sr(MoO4).CHINESE PHYSICS B,27(11),5.
MLA	Zhang, Ji,et al."Temperature-dependent Raman spectroscopic study of ferroelastic K2Sr(MoO4)".CHINESE PHYSICS B 27.11(2018):5.

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