The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins

doi:10.1080/10426507.2018.1493480

	The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins
	Yang, Xiaoling 1; Bai, Ying 1; Li, Jiayun 1; Liu, Yu 1; Peng, Jiajian 1; Li, Tianbo 2; Lang, Rui 2; Qiao, Botao 2
刊名	PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
	2019
卷号	194 期号:1-2 页码:83-86
关键词	Hydrosilylation titanium alkoxide alkali metal alkoxide olefin
ISSN号	1042-6507
DOI	10.1080/10426507.2018.1493480
通讯作者	Bai, Ying(ybai@hznu.edu.cn) ; Peng, Jiajian(jjpeng@hznu.edu.cn)
英文摘要	The catalytic activities of titanium alkoxides and alkali metal alkoxides for hydrosilylation of unfunctionalized olefins have been studied. Titanium(IV) alkoxides showed excellent catalytic activity, while alkali metal alkoxides have low catalytic activity for the hydrosilylation of olefins. However, by using titanocene dichloride as an additive, alkali metal alkoxides showed also excellent catalytic property for hydrosilylation. In comparison with titanium alkoxides, no -adduct was obtained by using alkali metal alkoxides/Cp2TiCl2 as catalysts.
WOS关键词	ALKENE HYDROSILYLATION ; COMPLEXES ; IRON ; REDUCTION
WOS研究方向	Chemistry
语种	英语
出版者	TAYLOR & FRANCIS LTD
WOS记录号	WOS:000469421300012
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/175874]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Bai, Ying; Peng, Jiajian
作者单位	1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Yang, Xiaoling,Bai, Ying,Li, Jiayun,et al. The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,2019,194(1-2):83-86.
APA	Yang, Xiaoling.,Bai, Ying.,Li, Jiayun.,Liu, Yu.,Peng, Jiajian.,...&Qiao, Botao.(2019).The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins.PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,194(1-2),83-86.
MLA	Yang, Xiaoling,et al."The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins".PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 194.1-2(2019):83-86.