Titanium-catalyzed hydrosilylation of olefins: A comparison study on Cp2TiCl2/Sm and Cp2TiCl2/LiAlH4 catalyst system

doi:10.1080/10426507.2018.1487440

	Titanium-catalyzed hydrosilylation of olefins: A comparison study on Cp2TiCl2/Sm and Cp2TiCl2/LiAlH4 catalyst system
	Yang, Xiaoling 1; Bai, Ying 1; Li, Jiayun 1; Liu, Yu 1; Peng, Jiajian 1; Li, Tianbo 2; Lang, Rui 2; Qiao, Botao 2
刊名	PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
	2019
卷号	194 期号:1-2 页码:64-68
关键词	Hydrosilylation titanocene samarium LiAlH4 mechanism TEMPO
ISSN号	1042-6507
DOI	10.1080/10426507.2018.1487440
通讯作者	Bai, Ying(ybai@hznu.edu.cn) ; Peng, Jiajian(jjpeng@hznu.edu.cn)
英文摘要	Hydrosilylation of olefins catalyzed by Cp2TiCl2/Sm (Cp=cyclopentadienyl) under solvent free conditions have been investigated. By using Cp2TiCl2/Sm as catalyst system, -adducts and hydrogenation products were detected. Hydrosilylation of olefins catalyzed by Cp2TiCl2/LiAlH4 under room temperature has also been studied. The influence of TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) on Cp2TiCl2/Sm and Cp2TiCl2/LiAlH4, respectively, indicated that hydrosilylation of olefins catalyzed with Cp2TiCl2/Sm went through a free radical reaction pathway while a coordination mechanism was applied for Cp2TiCl2/LiAlH4 catalyst system.
WOS关键词	ALKENE HYDROSILYLATION ; REDUCTION ; COMPLEXES ; ISOMERIZATION ; IRON ; HALIDES
WOS研究方向	Chemistry
语种	英语
出版者	TAYLOR & FRANCIS LTD
WOS记录号	WOS:000469421300009
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/175796]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Bai, Ying; Peng, Jiajian
作者单位	1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou, Zhejiang, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Yang, Xiaoling,Bai, Ying,Li, Jiayun,et al. Titanium-catalyzed hydrosilylation of olefins: A comparison study on Cp2TiCl2/Sm and Cp2TiCl2/LiAlH4 catalyst system[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,2019,194(1-2):64-68.
APA	Yang, Xiaoling.,Bai, Ying.,Li, Jiayun.,Liu, Yu.,Peng, Jiajian.,...&Qiao, Botao.(2019).Titanium-catalyzed hydrosilylation of olefins: A comparison study on Cp2TiCl2/Sm and Cp2TiCl2/LiAlH4 catalyst system.PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,194(1-2),64-68.
MLA	Yang, Xiaoling,et al."Titanium-catalyzed hydrosilylation of olefins: A comparison study on Cp2TiCl2/Sm and Cp2TiCl2/LiAlH4 catalyst system".PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 194.1-2(2019):64-68.