Zeolite-supported metal catalysts for selective hydrodeoxygenation of biomass-derived platform molecules

doi:10.1039/c9gc01216h

	Zeolite-supported metal catalysts for selective hydrodeoxygenation of biomass-derived platform molecules
	Luo, Wenhao 4; Cao, Wenxiu 2; Bruijnincx, Pieter C. A.1; Lin, Lu 4; Wang, Aiqin 3,4; Zhang, Tao 3,4
刊名	GREEN CHEMISTRY
	2019-07-21
卷号	21 期号:14 页码:3744-3768
ISSN号	1463-9262
DOI	10.1039/c9gc01216h
通讯作者	Luo, Wenhao(w.luo@dicp.ac.cn) ; Wang, Aiqin(aqwang@dicp.ac.cn) ; Zhang, Tao(taozhang@dicp.ac.cn)
英文摘要	Increasing demand for renewable chemicals and fuels has stimulated the search for alternative feedstocks and is driving the ongoing transition to a more renewables-based society. Considerable academic efforts have been directed at the valorisation of biomass sources and derived intermediates, so called platform molecules, to produce value-added chemicals and fuels. In this contribution, opportunities are discussed for the application of zeolite-supported bifunctional catalysts in the conversion of biomass sources into chemicals and fuels via hydrodeoxygenation (HDO). Such metal/zeolite catalyst systems play a prominent role in many of these biomass HDO routes. Emphasis is put on the current progress in metal/zeolite-catalysed HDO of three selected, promising routes involving biomass-derived platform molecules and the model compounds that mimic more complex feeds. Four key concepts of metal/zeolite catalysts, such as combining metal and Bronsted acid sites, site-ratio balancing, proximity between metal and acid functions and shape selectivity are discussed in order to provide a comprehensive overview. In addition, two challenges related to the accessibility of the active sites and catalyst stability in the liquid phase, typically a hot, highly polar, and protic reaction medium, are discussed. Finally, the open challenges and perspectives regarding the development of metal/zeolite catalysts for biomass HDO reactions are examined.
资助项目	National Key Projects for Fundamental Research and Development of China[2018YFB1501600] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801] ; National Natural Science Foundation of China[21703238] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21690084] ; National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21673228] ; National Natural Science Foundation of China[21802134] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100]
WOS关键词	VAPOR-PHASE HYDROGENATION ; DIESEL-RANGE ALKANES ; OIL MODEL COMPOUNDS ; LEVULINIC ACID ; GAMMA-VALEROLACTONE ; BIO-OIL ; BIFUNCTIONAL CATALYSTS ; CRYSTALLINE ALUMINOSILICATES ; HYDROTHERMAL STABILITY ; HYDROPHOBIC ZEOLITES
WOS研究方向	Chemistry ; Science & Technology - Other Topics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000475506200001
资助机构	National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173947]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Luo, Wenhao; Wang, Aiqin; Zhang, Tao
作者单位	1.Univ Utrecht, Organ Chem & Catalysis, Debye Inst Nanomat Sci, Univ Weg 99, NL-3584 CG Utrecht, Netherlands 2.Jishou Univ, Coll Chem & Chem Engn, Jishou 416000, Hunan, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Luo, Wenhao,Cao, Wenxiu,Bruijnincx, Pieter C. A.,et al. Zeolite-supported metal catalysts for selective hydrodeoxygenation of biomass-derived platform molecules[J]. GREEN CHEMISTRY,2019,21(14):3744-3768.
APA	Luo, Wenhao,Cao, Wenxiu,Bruijnincx, Pieter C. A.,Lin, Lu,Wang, Aiqin,&Zhang, Tao.(2019).Zeolite-supported metal catalysts for selective hydrodeoxygenation of biomass-derived platform molecules.GREEN CHEMISTRY,21(14),3744-3768.
MLA	Luo, Wenhao,et al."Zeolite-supported metal catalysts for selective hydrodeoxygenation of biomass-derived platform molecules".GREEN CHEMISTRY 21.14(2019):3744-3768.